Electrochemical carboxylation of acyl chlorides, freons, and halogen-containing polymers

V. G. Koshechko V. G. Koshechko , V. E. Titov V. E. Titov , V. A. Lopushanskaya V. A. Lopushanskaya
Российский электрохимический журнал
Abstract / Full Text

Processes of the carbon dioxide fixation are studied. The fixation is done by an electrochemical carboxylation of chlorides of aliphatic and aromatic carboxylic acids (acetyl chloride, benzoyl chloride and its derivatives), halogen-containing polymers (polyvinyl chloride, polyvinyl bromide), polybutadiene, and polyfluoroalkyl halides (CF3Br, CF3I, C3F7I). Major effects of some factors (reagent electronic structure, electrode materials, supporting electrolyte) on the occurrence of such processes and the yield of target products are studied.

Author information
  • Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine

    V. G. Koshechko, V. E. Titov & V. A. Lopushanskaya

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