Статья
2017

Electrochemical dehalogenation of polytrifluorochloroethylene


A. A. Stepanov A. A. Stepanov , M. I. Buzin M. I. Buzin , E. G. Kononova E. G. Kononova , V. E. Sosenkin V. E. Sosenkin , Yu. M. Vol’fkovich Yu. M. Vol’fkovich
Российский электрохимический журнал
https://doi.org/10.1134/S1023193517050135
Abstract / Full Text

The electrochemical reduction of polytrifluorochloroethylene suspended in an electrolyte using organic electron transfer mediators led to surface modification of the polymer. Pyrolysis of the reduction product was accompanied by the formation of a highly porous thermally stable polycarbon material with pore sizes in a very wide range, approximately from 1 to 105 nm.

Author information
  • Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russia

    A. A. Stepanov, M. I. Buzin & E. G. Kononova

  • Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119071, Russia

    V. E. Sosenkin & Yu. M. Vol’fkovich

References
  1. Stepanov, A.A., Lenenko, N.D., Golub’, A.S., and Pervov, V.S., Russ. J. Electrochem., 2013, vol. 49, p. 86.
  2. Gol’din, M.M., Feoktistov, L.G., Tomilov, A.P., and Smirnov, K.M., Zh. Obshch. Khim., 1972, vol. 47, p. 2561.
  3. Bazhina, E., Aleksandrov, G., Bogomyakov, A., Kiskin, M., Masoud, S., Nikitin, O., Magdesieva, T., Sidorov, A., and Eremenko, I., Polyhedron, 2014, vol. 77, p. 47.
  4. Volfkovich, Yu.M., Sosenkin, V.E., and Bagotsky, V.S., J. Power Sources, 2010, vol. 195, p. 5429.
  5. Volfkovich, Yu.M., Bagotzky, V.S., Sosenkin, V.E., and Blinov, I.A., Colloids Surf., A, 2001, vol. 187, p. 349.
  6. Volfkovich, Yu.M. and Bagotzky, V.S., J. Power Sources, 1994, vol. 48, p. 327.
  7. Rouquerol, J., Baron, G., Denoyel, R., Giesche, H., Groen, J., Klobes, P., Levitz, P., Neimark, A.V., Rigby, S., Skudas, R., Sing, K., Thommes, M., and Unger, K., Pure Appl. Chem., 2011, vol. 84, p. 107.
  8. Stepanov, A.A., J. Fluorine Chem., 2002, vol. 114, p. 225.
  9. Krivenko, A.G., Tomilov, A.P., Smirnov, Yu.D., Kotkin, A.S., and Kurmaz, V.A., Russ. J. Gen. Chem., 1998, vol. 68, p. 266.
  10. Baizer, M.M. and Lund, H.N.Y., Eds., Organic Electrochemistry, New York: Marcel Dekker, 1983.