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Статья
2000

Step wise and dissociative mechanisms of the electron transfer in electrochemical reactions involving organosilicon compounds: Molecular-thermodynamic approach1

V. V. ZhuikovV. V. Zhuikov
Российский электрохимический журнал
https://doi.org/10.1007/BF02756895
Abstract / Full Text
Zhuikov, V.V. Step wise and dissociative mechanisms of the electron transfer in electrochemical reactions involving organosilicon compounds: Molecular-thermodynamic approach1. Russ J Electrochem 36, 117–127 (2000). https://doi.org/10.1007/BF02756895

Electrochemical reduction of organochlorosilanes and oxidation of hexaorganodisilanes may occur via dissociative and stepwise mechanisms, the choice between which is determined by the balance between fundamental structural parameters of elementoorganic molecules. The formation of radical anions of silyl-substituted chloromethane in the conditions of an electrochemical experiment is shown. The formation is due to α-silicon stabilization of the intermediate during the electron transfer. The role of conjugation and hyperconjugation in the organosilicon compounds’ reactivity is analyzed.

Author information
  • Kazan State University, ul. Lenina 18, Kazan, 420008, Tatarstan, RussiaV. V. Zhuikov
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