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Статья
2022

Extraction of Actinides and Lanthanides from Nitric Acid Solutions with Polyphosphinylbenzenes


A. N. TaranovA. N. Taranov, V. K. KarandashevV. K. Karandashev, V. K. BrelV. K. Brel
Российский журнал общей химии
https://doi.org/10.1134/S1070363222080163
Abstract / Full Text

The extraction of trace amounts of U(VI), Th(IV), Am(III), and lanthanides(III) from nitric acid solutions with polyphosphinylbenzenes was studied. The stoichiometry of the extracted complexes was determined, and the influence of the extractant structure, the HNO3 concentration in the aqueous phase, and the nature of organic solvents on the efficiency of metal ions extraction into the organic phase was considered. It was found that compounds with diphenylphosphoryl groups attached directly to the benzene ring in the ortho position in their molecules have the highest extraction ability with respect to actinides and lanthanides.

Author information
  • Yu.A. Ossipyan Institute of Solid State Physics of the Russian Academy of Sciences, 142432, Chernogolovka, RussiaA. N. Taranov
  • Institute of Problems of Microelectronics Technology and Especially Pure Materials of the Russian Academy of Sciences, 142432, Chernogolovka, RussiaV. K. Karandashev
  • A.N. Nesmeaynov Institute of Organoelement Compounds of the Russian Academy of Sciences, 119991, Moscow, RussiaO. I. Artyushin & V. K. Brel
  • A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences, 119991, Moscow, RussiaG. V. Kostikova & A. M. Fedoseev
References
  1. Rozen, A.M. and Krupnov, B.V., Russ. Chem. Rev., 1996, vol. 65, no. 11, p. 973. https://doi.org/10.1070/RC1996v065n11ABEH000241
  2. Siddall, T.H., J. Inorg. Nucl. Chem., 1963, vol. 25, p. 883. https://doi.org/10.1016/0022-1902(63)80376-0
  3. Mrochek, J.E. and Banks, V.C., J. Inorg. Nucl. Chem., 1965, vol. 27, p. 589. https://doi.org/10.1016/0022-1902(65)80265-2
  4. Rozen, A.M, Nikolotova, Z.I., Kartasheva, N.A., and Yudina, K.S., Dokl. AN SSSR, 1975, vol. 222, no. 5, p. 1151.
  5. Rozen, A.M, Nikolotova, Z.I., and Kartasheva, N.A., Radiokhimiya, 1986, vol. 28, no. 3, p. 407.
  6. Rozen, A.M., Volk, V.I., Vakhrushin, A.Yu., Zakharkin, B.S., Kartasheva, N.A., Krupnov, B.V., and Nikolotova, Z.I., Radiochemistry, 1999, vol. 41, no. 3, p. 215.
  7. Kabachnik, M.I., Myasoyedov, B.F., Mastryukova, T.A., Polikarpov, Yu.M., Chmutova, M.K., and Nesterova, N.P., Izv. AN, Ser. Khim., 1996, no. 11, p. 2624.
  8. Tsvetkov, E.N., Evreinov, V.I., Bondarenko, N.A., and Safronova, Z.V., Zh. Obshch. Khim., 1996, vol. 66, no. 7, p. 1081.
  9. Sudarushkin, S.K., Morgalyuk, V.P., Tananaev, I.G., Gribov, L.A., and Myasoyedov, B.F., Izv. AN, Ser. Khim., 2006, no. 4, p. 609.
  10. Leoncini, A., Huskens, J., and Verboom, W., Chem. Soc. Rev., 2017, vol. 46, p. 7229. https://doi.org/10.1039/C7CS00574A
  11. Wilson, A.M., Bailey, P.J., and Tasker, P.A., Chem. Soc. Rev., 2014, vol. 43, p. 123. https://doi.org/10.1039/C3CS60275C
  12. Werner, E.J. and Biros, S.M., Org. Chem. Front., 2019, vol. 6, p. 2067. https://doi.org/10.1039/C9QO00242A
  13. Alyapyshev, M.Yu., Babain, V.A., and Ustynyuk, Yu.A., Russ. Chem. Rev., 2016, vol. 85, no. 9, p. 943. https://doi.org/10.1070/RCR4588
  14. Ansari, S.A., Mohapatra, P.K., Leonchini, A., Huskens, J., and Verboom, W., Dalton Trans., 2017, vol. 46, p. 11355. https://doi.org/10.1039/C7DT01954H
  15. Ansari, S.A., Leonchini, A., Mohapatra, P.K., Huskens, J., and Verboom, W., Dalton Trans., 2018, vol. 47, p. 13631. https://doi.org/10.1039/C8DT02750A
  16. Turanov, A.N., Karandashev, V.K., Artyushin, O.I., and Brel, V.K., Solvent Extr. Ion Exch., 2020, vol. 38, p. 166. https://doi.org/10.1080/07366299.2019.1708001
  17. Myasoedov, B.F., Bodrin, G.V., Chmutova, M.K., Kochetkova, N.E., Medved’, T.Ya., Polykarpov, Yu.M., and Kabachnik, M.I., Solvent Extr. Ion Exch., 1983, vol. 1, p. 689.
  18. Rozen, A.M., Berkman, Z.A., Bertina, L.E., Denisov, D.A., Zarubin, A.I., Kossykh, V.G., Nikolotova, Z.I., and Yudina, K.S., Radiokhimiya, 1976, vol. 18, no. 4, p. 493.
  19. Rozen, A.M., Nikolotova, Z.I., Kartasheva, N.A., Medved’, T.Ya., Nesterova, N.P., Yudina, K.S., and Kabachnik, M.I., Radiokhimiya, 1976, vol. 18, no. 6, p. 846.
  20. Chmutova, M.K., Bodrin, G.V., Litvina, M.N., Matveeva, A.G., Matrosov, Y.I., Polikarpov, Yu.M., Khizhnyak, P.L., Myasoedov, B.F., and Kabachnik, M.I., Radiochemistry, 1989, vol. 31, no. 1, p. 83.
  21. Rozen, A.M., Radiokhimiya, 1990, vol. 19, no. 4, p. 54.
  22. Turanov, A.N., Karandashev, V.K., Baulin, V.E., Kirillov, E.V., Kirillov, S.V., Rychkov, V.N., and Tsivadze, A.Yu., Russ. J. Inorg. Chem., 2015, vol. 60, no. 8, p. 1015. https://doi.org/10.1134/S0036023615080203
  23. Turanov, A.N., Karandashev, V.K., Baulin, V.E., Yarkevich, A.N., and Safronova, Z.V., Solvent Extr. Ion Exch., 2009, vol. 27, p. 551. https://doi.org/10.1080/07366290903044683
  24. Horwitz, E.P., Martin, K. A., Diamond, H., and Kaplan, L., Solv. Extr. Ion Exch., 1986, vol. 4, no. 3, p. 449. https://doi.org/10.1080/07366298608917877
  25. Nash, K.L. and Jensen, M.P., Sep. Sci. Technol., 2001, vol. 36, nos. 5–6, p. 1257. https://doi.org/10.1081/SS-100103649
  26. Shadrin, A.Yu., Babain, V.A., and Kiseleva, R.N., Radiokhimiya, 1993, vol. 35, no. 1, p. 45.
  27. Shadrin, A.Yu., Smirnov, I.V., Kiseleva, R.N., Nesterova, N.P., Polikarpov, Yu.M., and Kabachnik, M.I., Radiokhimiya, 1993, vol. 35, no. 1, p. 51.
  28. Turanov, A. N., Karandashev, V. K., Kharitonov, A.V., Safronova, Z.V., and Yarkevich, A. N., Radiokhimiya, 2000, vol. 42, no. 4, p. 349.
  29. Matveeva, A.G., Artyushin, O.I., Pasechnik, M.P., Stash, A.I., Vologzhanina, A.V., Matveev, S.V., Godovikov, I.A., Aysin, R.R., Moiseeva, A.A., Turanov, A.N., Karandashev, V.K., and Brel, V.K., Polyhedron, 2021, vol. 198. 115085. https://doi.org/10.1016/j.poly.2021.115085
  30. Ban, X., Sun, Y., Huang, B., and Jiang, W., Org. Electronics, 2016, vol. 33, p. 9. https://doi.org/10.1016/j.orgel.2016.02.041