Статья
2022
Extraction of Actinides and Lanthanides from Nitric Acid Solutions with Polyphosphinylbenzenes
A. N. Taranov, V. K. Karandashev, V. K. Brel
Российский журнал общей химии
https://doi.org/10.1134/S1070363222080163
Abstract / Full Text
The extraction of trace amounts of U(VI), Th(IV), Am(III), and lanthanides(III) from nitric acid solutions with polyphosphinylbenzenes was studied. The stoichiometry of the extracted complexes was determined, and the influence of the extractant structure, the HNO3 concentration in the aqueous phase, and the nature of organic solvents on the efficiency of metal ions extraction into the organic phase was considered. It was found that compounds with diphenylphosphoryl groups attached directly to the benzene ring in the ortho position in their molecules have the highest extraction ability with respect to actinides and lanthanides.
Author information
- Yu.A. Ossipyan Institute of Solid State Physics of the Russian Academy of Sciences, 142432, Chernogolovka, RussiaA. N. Taranov
- Institute of Problems of Microelectronics Technology and Especially Pure Materials of the Russian Academy of Sciences, 142432, Chernogolovka, RussiaV. K. Karandashev
- A.N. Nesmeaynov Institute of Organoelement Compounds of the Russian Academy of Sciences, 119991, Moscow, RussiaO. I. Artyushin & V. K. Brel
- A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences, 119991, Moscow, RussiaG. V. Kostikova & A. M. Fedoseev
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