Examples



mdbootstrap.com



 
Статья
2021

Synthesis, Crystal Structures, and Magnetic Properties of Two Manganese(II)/Cobalt(II) Coordination Polymers Constructed by Nitrogenous Carboxylic Acid


Y. P. LiY. P. Li, G. L. LiG. L. Li, L. Y. XinL. Y. Xin, X. L. LiX. L. Li, G. Z. LiuG. Z. Liu
Российский журнал общей химии
https://doi.org/10.1134/S1070363221070197
Abstract / Full Text

Two new coordination polymers, {[Mn2(L)(H2O)2]·H2O}n (1) and {[Co2(L)(H2O)2]·H2O}n (2) (H4L = 2-(2,4,6-tricarboxylphenyl)-6-carbxoylbenzimi-dazole), have been synthesized under hydrothermal conditions and characterized by element analysis, powder XRD and single crystal X-ray diffraction. The results indicate complex 1 as a 2D carboxylate layer structure, which is extended by hydrogen bonds resulting in a three-dimensional supramolecular network. The structure of 2 is isomorphic to that of 1. Magnetic measurements demonstrate weak antiferromagnetic interactions between the neighbouring Mn(II) ions in 1.

Author information
  • College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal University, 471934, Luoyang, ChinaY. P. Li, G. L. Li, L. Y. Xin, X. L. Li & G. Z. Liu
References
  1. Zhao, Y., Deng, D.S., Ma, L.F., Ji, B.M., and Wang, L.Y., Chem. Commun., 2013, vol. 49, p. 10299. https://doi.org/10.1039/C3CC45310C
  2. Qin, J.H., Ma, L.F., Hu, Y., and Wang, L.Y., Cryst. Eng. Comm., 2012, vol. 14, p. 2891. https://doi.org/10.1039/C2CE06581A
  3. Li, Y.P., Ju, F.Y., Li, G.L., Xin, L.Y., Li, X.L., and Liu, G.Z., Russ. J. Coord. Chem., 2018, vol. 44, p. 214. https://doi.org/10.1134/S1070328418030028
  4. Liu, G.Z., Li, X.D., Li, X.L., and Wang, L.Y., Cryst. Eng. Comm., 2013, vol. 15, p. 2428. https://doi.org/10.1039/C3CE26781D
  5. Miao, S.B., Li, Z., Xu, C.Y., and Ji, B.M., Cryst. Eng. Comm., 2016, vol. 18, p. 4636. https://doi.org/10.1039/C6CE00625F
  6. Murray, L.J., Dinca, M., Yano, J., Chavan, S., Bordiga, S., Brown, C.M., and Long, J.R., J. Am. Chem. Soc., 2010, vol. 132, p. 7856. https://doi.org/10.1021/ja1027925
  7. He, Y.B., Zhou, W., Qian G.D., and Chen, B.L., Chem. Soc. Rev., 2014,vol. 43, p. 5657. https://doi.org/10.1039/C4CS00032C
  8. Li, X. L., Liu, G.Z., Xin, L.Y., and Wang, L.Y., J. Solid State Chem., 2017, vol. 246, p. 252. https://doi.org/10.1016/j.jssc.2016.11.030
  9. Wang, Y.F., Li, M.H., and Wang, LY., Russ. J. Gen. Chem., 2020, vol. 90, p. 305. https://doi.org/10.1134/S1070363220020231
  10. Du, LT.., Lu, Z.Y., Zheng, K.Y., Wang, J.Y., Zheng, X., Pan, Y., You, X.Z., and Bai, J.F., J. Am. Chem. Soc., 2013, vol. 135, p. 562. https://doi.org/10.1021/ja309992a
  11. Ju, F.Y. and Li, S., Russ. J. Gen. Chem., 2020, vol. 90, p. 1083. https://doi.org/10.1134/S1070363220060237
  12. Lin, J.D., Long, X.F., Lin, P., and Du, S.W., Cryst. Growth Des., 2010, vol. 10, p. 146. https://doi.org/10.1021/cg9007476
  13. Qiu, S.L. and Zhu, G.S., Coord. Chem. Rev., 2009, vol. 253, p. 2891. https://doi.org/10.1016/j.ccr.2009.07.020
  14. Deng, D.S., Liu, L.L., Ji, B.M., Yin, G.J., and Du, C.X., Cryst. Growth Des., 2012, vol. 12, p. 5338. https://doi.org/10.1021/cg300900m
  15. Li, F.F. and Lu, L.P., Chinese J. Struct. Chem., 2019, vol. 38, p. 1814.
  16. Sheldrick, G.M., SHELXS-97, Program for Crystal Structure Solution, Göttigen, University of Göttigen, 1997.
  17. Ju, F.Y., Li, Y.P., Li, G.L., Liu, G.Z., Chinese J. Struct. Chem., 2016, vol. 35, p. 404. https://doi.org/10.14102/j.cnki.0254-5861.2011-0866
  18. Li, G.L., Liu, G.Z., Huang, L.L., and Li, Z.X., Chinese J. Struct. Chem., 2014, vol. 33, p. 942. https://doi.org/
  19. Wang, Y.F. and Zhang, Y.H., Inorg. Nano-Metal Chem., 2021, vol. 21, p. 303. https://doi.org/10.1080/24701556.2020.1786119
  20. Wang, Y.F., Li, Y.Y., Zhao, J.S., and Wang, L.Y., Z. Anorg. Allg. Chem., 2012, vol. 638, p. 658. https://doi.org/10.1002/zaac.201100460
  21. Xin, L.Y., Liu, G.Z., Li, X.L., and Wang, L.Y., Cryst. Growth Des., 2012, vol. 12, p.147. https://doi.org/10.1021/cg200903k