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Статья
2016

Ion conductivity of perovskites CaZr1 – x Sc x O3 – α (x = 0.03–0.20) in hydrogen-containing atmospheres

V. P. GorelovV. P. Gorelov, V. B. BalakirevaV. B. Balakireva, A. V. Kuz’minA. V. Kuz’min
Российский электрохимический журнал
https://doi.org/10.1134/S1023193516110069
Abstract / Full Text
Gorelov, V.P., Balakireva, V.B. & Kuz’min, A.V. Ion conductivity of perovskites CaZr1 – x Sc x O3 – α (x = 0.03–0.20) in hydrogen-containing atmospheres. Russ J Electrochem 52, 1076–1081 (2016). https://doi.org/10.1134/S1023193516110069

The total, proton, and oxygen conductivities in the CaZr1–x Sc x O3–α system (x = 0.03–0.20) were studied experimentally in the reductive atmospheres H2 + H2O + N2 in the temperature range 600–900°C. The electric conductivity and the transport numbers of ions and protons were measured using the direct current four-probe method and the EMF method with oxygen and water vapor concentration cells, respectively. The materials under study are pure proton-conductive below 700°C in these atmospheres; at higher temperatures, a pronounced contribution of oxygen conductivity appears. The isotherms of the total and partial conductivities are symbatic and have a maximum between x = 0.05 and x = 0.10, which correlates with the position of the boundary of the single-phase state.

Author information
  • Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620137, RussiaV. P. Gorelov, V. B. Balakireva & A. V. Kuz’min
  • Ural Federal University named after the first President of Russia B.N. Yeltsin, Yekaterinburg, 620002, RussiaA. V. Kuz’min
References
  1. Kreuer, K.D., Chem. Mater., 1996, vol. 8, p. 610.
  2. Pal’guev, S.F., Vysokotemperaturnye protonnye tverdye elektrolity (High-Temperature Proton Solid Electrolytes), Yekaterinburg: Ural Branch, Russian Academy of Sciences, 1998.
  3. Norby, T., Solid State Ionics, 1999, vol. 125, p. 1.
  4. Schober, T., Solid State Ionics, 2003, vols. 162–163, p. 277.
  5. Ivanov-Shits, A. and Murin, I., Ionika tverdogo tela (Solid State Ionics), St. Petersburg: S.-Peterb. Univ., 2010, vol. 2.
  6. Malavasi, L., Fisher, C.A., and Islam, M.S., Chem. Soc. Rev., 2010, vol. 39, p. 4370.
  7. Tanaka, M., Katahira, K., Asakura, Y., Uda, T., Iwahara, H., and Yamamoto, I., J. Nucl. Sci. Technol., 2004, vol. 41, p. 61.
  8. Shi, Ch., Yoshino, M., and Morinaga, M., Solid State Ionics, 2005, vol. 176, p. 1091.
  9. Kurita, N., Xiong, Yue-P., Imai, Y., and Fukatsu, N., Ionics, 2010, vol. 16, p. 787.
  10. Suzuki, A., Muroga, T., Yoneoka, T., and Tanaka, S., J. Phys. Chem. Solids, 2005, vol. 66, p. 690.
  11. Kondo, M., Muroga, T., Katahira, K., and Oshima, T., J. Power Energy Syst., 2008, vol. 2, p. 590.
  12. Kurita, N., Fukatsu, N., Ito, K., and Ohashi, T., J. Electrochem. Soc., 1995, vol. 142, p. 1552.
  13. Gorelov, V.P., Vykhodetz, V.B., Kurennykh, T.E., Balakireva, V.B., Kuz’min, A.N., and Anan’ev, M.V., Russ. J. Electrochem., 2013, vol. 49, p. 915.
  14. Gorelov, V.P., Balakireva, V.B., Kuz’min, A.V., and Plaksin, S.V., Neorg. Mater., 2014, vol. 50, p. 535.
  15. Gorelov, V.P., Balakireva, V.B., and Kuz’min, A.V., Fiz. Tverd. Tela, 2016, vol. 58, p. 14.
  16. Gorelov, V.P. and Balakireva, V.B., Izv. Akad. Nauk SSSR, Neorg. Mater., 1990, vol. 26, p. 102.
  17. Anan’ev, M.V., Bershitskaya, N.M., Plaksin, S.V., and Kurumchin, E.H., Russ. J. Electrochem., 2012, vol. 48, p. 879.
  18. Gorelov, V.P., Sharova, N.V., and Sokolova, Yu.V., Russ. J. Electrochem., 1997, vol. 33, p. 1351.
  19. Arestova, N.V. and Gorelov, V.P., Elektrokhimiya, 1994, vol. 30, p. 988.
  20. Fadeev, G.I., Volkov, A.N., Kalyakin, A.S., Demin, A.K., Gorelov, V.P., Neuimin, A.D., and Balakireva, V.B., RF Patent 2483298, 2013.
  21. Demin, A.K., Volkov, A.N., Kalyakin, A.S., Fadeev, G.I., Gorelov, V.P., and Kuz’min, A.V., RF Patent 2483300, 2013.
  22. Volkov, A.N., Kalyakin, A.S., Fadeev, G.I., Demin, A.K., and Gorelov, V.P., RF Patent 2490623, 2013.
  23. Bao, J., Ohno, H., Kurita, N., Okuyama, Y., and Fukatsu, N., Electrochim. Acta, 2011, vol. 56, p. 1062.
  24. Kreuer, K.D., Ann. Rev. Mater. Res., 2003, vol. 33, p. 333.
  25. Islam, M.S., Davies, R.A., and Gale, J.D., Chem. Mater., 2001, vol. 13, p. 2049.
  26. Løken, A., Kjølseth, Ch., and Haugsrud, R., J. Alloys Compd., 2014, vol. 267, p. 61.
  27. Balakireva, V.B., Kuz’min, A.V., and Gorelov, V.P., Russ. J. Electrochem., 2010, vol. 46, p. 749.