Oxidation of Bisphenol A in a Hybrid Oxidative System, Based on the Combined Action of Acoustic and Low-Pressure Hydrodynamic Cavitation
D. G. Aseev, A. A. Batoeva
Российский журнал физической химии А
https://doi.org/10.1134/S0036024421100022
Kinetic patterns are found for the destruction of Bisphenol A (BPA) with the participation of highly reactive oxygen-containing radicals generated in situ in an aqueous medium under the action of acoustic cavitation in a megahertz range (1.7 MHz) and low pressure hydrodynamic cavitation (LPHC). It is shown that the considered oxidative systems can be ranked according to the efficiency and rate of destruction of BPA: LPHC/US/Fe2+/S2O\(_{8}^{{2 - }}\) > US/Fe2+/S2O\(_{8}^{{2 - }}\) > /Fe2+/S2O\(_{8}^{{2 - }}\) > LPHC/US/S2O\(_{8}^{{2 - }}\) > LPHC/US > LPHC. It is concluded that a synergistic effect reveals substantial activation of the oxidation of BPA under the combined action of high-frequency ultrasound and LPHC in an LPHC/US/Fe2+/S2O\(_{8}^{{2 - }}\) Fenton-like iron–persulfate system. It is found that full conversion of BPA in an LPHC/US/Fe2+/S2O\(_{8}^{{2 - }}\) hybrid oxidative system is achieved after 240 min of treatment, and the mineralization of the organic substance is 60%.
- Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Sciences, 670047, Ulan-Ude, RussiaD. G. Aseev & A. A. Batoeva
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