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Статья
2020

Molecular Interactions of L-Histidine in an Aqueous Buffer Solution in the Temperature Range of 288–313 K


E. Yu. TyuninaE. Yu. Tyunina, V. G. BadelinV. G. Badelin, A. A. KuritsynaA. A. Kuritsyna
Российский журнал физической химии А
https://doi.org/10.1134/S0036024420040226
Abstract / Full Text

The behavior of L-histidine (His) in an aqueous buffer solution (pH 7.4) is studied via densimetry and differential scanning calorimetry. The densities and specific heat capacities of solutions of the amino acid are determined in the 288.15–313.15 K range of temperatures at His concentrations of 0.00215 to 0.03648 mol kg−1. The apparent and partial molar parameters of L-histidine in the buffer solution are found, and features of the temperature and concentration dependences are identified. It is shown that the partial molar properties of transferring the amino acid from water to the buffer solution (both volume and heat capacity) have positive values in the investigated range of temperatures. Different types of molecular interaction between the solute and the solvent are considered using the Gurney model.

Author information
  • Krestov Institute of Solution Chemistry, Russian Academy of Sciences, 153045, Ivanovo, RussiaE. Yu. Tyunina & V. G. Badelin
  • Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, RussiaA. A. Kuritsyna
References
  1. Y. Yasuda, N. Tochio, M. Sakurai, and K. Nitta, J. Chem. Eng. Data 43, 205 (1998).
  2. D. Kumar, S. K. Lomesh, and V. Nathan, J. Mol. Liq. 247, 75 (2017).
  3. P. L. Privalov, J. Solution Chem. 44, 1141 (2015).
  4. Y. Akhtar and S. F. Ibrahim, Arab. J. Chem. 4, 487 (2011).
  5. T. S. Banipal, N. Kaur, and P. K. Banipal, J. Chem. Thermodyn. 82, 12 (2015).
  6. A. K. Nain, R. Pal, and R. K. Sharma, J. Mol. Liq. 165, 154 (2012).
  7. H. Kumar, M. Singla, and R. Jindal, J. Chem. Thermodyn. 70, 190 (2014).
  8. M. Taha and M.-J. Lee, J. Chem. Thermodyn. 41, 705 (2009).
  9. J. J. Jardine, T. G. Call, B. A. Patterson, M. L. Origlia-Luster, and E. M. Woolley, J. Chem. Thermodyn. 33, 1419 (2001).
  10. A. T. Riyazuddeen, Thermochim. Acta 501, 72 (2010).
  11. T. S. Banipal, K. Singh, and P. K. Banipal, J. Solution Chem. 36, 1635 (2007).
  12. A. L. Hansena and L. E. Kaya, Proc. Natl. Acad. Sci. U. S. A., E1705 (2014). www.pnas.org/cgi/doi/ 10.1073/pnas.1400577111
  13. Y. Oya-Ohta, T. Ochi, Y. Komoda, and K. Yamamoto, Mutat. Res. 326, 99 (1995).
  14. R. K. Chernova, O. V. Varygina, and N. S. Berezkina, Izv. Sarat. Univ., Nov. Ser., Ser.: Khim. Biol. Ekol. 15 (4), 15 (2015).
  15. E. Yu. Tyunina, V. G. Badelin, and I. N. Mezhevoi, J. Solution Chem. 46, 249 (2017).
  16. E. C. W. Clarke and D. N. Glew, J. Phys. Chem. Ref. Data 14, 490 (1985).
  17. Y. Miao, T. A. Cross, and R. Fu, J. Magn. Reson. 245, 105 (2014).
  18. C. Bretti, R. M. Cigala, O. Giuffre, G. Lando, and S. Sammartano, Fluid Phase Equilib. 459, 51 (2018).
  19. V. P. Vasil’ev, V. A. Borodin, and E. V. Kozlovskii, Computers in Calculations in Analytical Chemistry (Vysshaya Shkola, Moscow, 1993) [in Russian].
  20. N. Sawheney, M. Kumar, A. K. Sharma, and M. Sharma, J. Chem. Thermodyn. 115, 156 (2017).
  21. A. Stefaniu and O. Iulian, J. Solution Chem. 42, 2384 (2013).
  22. V. G. Badeline, E. Yu. Tyunina, I. N. Mezhevoi, and G. N. Tarasova, Russ. J. Phys. Chem. A 89, 2229 (2015).
  23. R. W. Gurney, Ionic Processes in Solution (McGraw Hill, New York, 1953).
  24. F. Franks, Water: A Comprehensive Treatise (Plenum, New York, 1973), Vol. 3.
  25. H. Kumar and K. Kaur, J. Chem. Thermodyn. 5, 86 (2012).
  26. I. V. Terekhova and O. V. Kulikov, Mendeleev Commun. 3, 1 (2002).
  27. L. Lepori and P. Gianni, J. Solution Chem. 29, 405 (2000).
  28. L. G. Hepler, Can. J. Chem. 47, 4613 (1969).
  29. V. P. Vasil’ev, Thermodynamic Properties of Electrolyte Solutions (Vysshaya Shkola, Moscow, 1982) [in Russian].
  30. V. A. Latysheva, Usp. Khim. 42, 1757 (1973).
  31. R. A. Marriott, Theses (Univ. of Lethbridge, 1999). https://hdl.handle.net/10133/91.
  32. E. Yu. Tyunina, Russ. J. Phys. Chem. A 93, 450 (2019).
  33. M. M. H. Bhuiyan, A. W. Hakin, and J. L. Liu, J. Solution Chem. 39, 877 (2010).
  34. B. Madan and K. A. Sharp, J. Phys. Chem. B 105, 2256 (2001).
  35. P. K. Banipal, T. S. Banipal, J. C. Ahluwalia, and B. S. Lark, J. Chem. Thermodyn. 34, 1825 (2002).
  36. R. V. Jasra and J. C. Ahluwalia, J. Solution Chem. 11, 325 (1982).
  37. B. Madan and K. A. Sharp, Biophys. J. 81, 1881 (2001).
  38. B. S. Lark, P. Patyar, T. S. Banipal, and N. Kishore, J. Chem. Eng. Data 49, 553 (2004).