Статья
2020

Study of the Effect of Inhibitor on the Corrosion Behavior of Steel Using Chebyshev Noise Spectroscopy and Electrochemical Impedance Spectroscopy

A. L. Klyuev A. L. Klyuev , V. N. Andreev V. N. Andreev , A. D. Davydov A. D. Davydov , B. M. Grafov B. M. Grafov
Российский электрохимический журнал
https://doi.org/10.1134/S1023193520120095
Abstract / Full Text
Klyuev, A.L., Andreev, V.N., Davydov, A.D. et al. Study of the Effect of Inhibitor on the Corrosion Behavior of Steel Using Chebyshev Noise Spectroscopy and Electrochemical Impedance Spectroscopy. Russ J Electrochem 56, 1011–1017 (2020). https://doi.org/10.1134/S1023193520120095

The electrochemical noise of a system of two identical steel electrodes in the NaCl solution without and with an addition of benzotriazole (BTA) corrosion inhibitor is measured and analyzed. It is shown that this method is a convenient tool for testing the protective properties of inhibitor. The method of impedance spectroscopy applied to this electrochemical system gives the information on the mechanism of inhibitor action.

Author information

  • Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    A. L. Klyuev, V. N. Andreev, A. D. Davydov & B. M. Grafov

References
  1. Mansfeld, F., The electrochemical noise technique—application in corrosion research, Proc. 18th International Conference on Noise and Fluctuations—ICNF 2005, Gonzalez, T, Mateos, J., and Pardo, D., Eds., American Institute of Physics, 2005, p. 625.
  2. Electrochemical Noise Measurement for Corrosion Applications, Kearns, R., Scully, J.R., Robege, P.R., Rei-chert, D.L., and Dawson, J.L., Eds., West Conshohocken, PA: ASTM, 1994.
  3. Huet, F., Electrochemical noise technique, in Analytical Methods in Corrosion Science and Engineering, Marcus, P. and Mansfeld, F., Eds., Boca Raton: CRC Press, 2006, p. 508.
  4. Cottis, R.A., Interpretation of EN data, Corrosion, 2001, vol. 57, p. 265.
  5. Cottis, R. and Turgoose, S., Electrochemical Impedance and Noise. Corrosion Testing Made Easy, Syrett, B.C., Series Ed., Houston, TX: NACE International, 1999.
  6. Tan, Y.J., Baile, S., and Kinsella, B., The monitoring of the formation and destruction of corrosion inhibitor films using ENA, Corros. Sci., 1996, vol. 38, p. 1681.
  7. Tan, Y.J., Kinsella, B., and Bailey, S., Monitoring batch treatment inhibitor performance using ENA, Br. Corros. J., 1997, vol. 32, p. 212.
  8. Nagiub, A.M., Electrochemical noise analysis for different green corrosion inhibitors for copper exposed to chloride media, Port. Electrochim. Acta, 2017, vol. 35, p. 201.
  9. Tan, Y., Heterogeneous Electrode Processes and Localized Corrosion, Hoboken, NJ: Wiley, 2013.
  10. Hermoso-Diaz, I.A., Gonzalez-Rodrigues, J.G., and Uruchuru-Chavarin, J., Use of EIS and electrochemical noise fractal analysis to study Salvia hispanica as green corrosion inhibitor for carbon steel, Int. J. Electrochem. Sci., 2016, vol. 11, p. 4253.
  11. Slavcheva, E. and Schmitt, G., Screening of new corrosion inhibitors via electrochemical noise analysis, Mater. Corros., 2002, vol. 53, p. 647.
  12. Ehsani, A., Mahjani, M.G., Hosseini, M., Safari, R., Moshrefi, R., and Shiri, H.M., Evaluation of Thymus vulgaris plant extract an eco-friendly corrosion inhibitor for stainless steel 304 in acidic solution by mean of electrochemical impedance spectroscopy, electrochemical noise analysis and density functional theory, J. Colloid Interface Sci., 2017, vol. 490, p. 444.
  13. Mehdipour, M., Ramezanzadeh, B., and Arman, S., Electrochemical noise investigation of Aloe plant extract as green inhibitor on the corrosion of stainless steel in 1 M H2SO4, J. Ind. Eng. Chem., 2015, vol. 21, p. 318.
  14. Lucio-Garcia, M.A., Gonzalez-Rodrigues, J.G., Martinez-Villafane, A., Dominguez-Patino, G., Neri-Flores, M.A., and Chacon-Nava, J.G., A study of hydroxyethyl imidazoline as H2S corrosion inhibitor using electrochemical noise and electrochemical impedance spectroscopy, J. Appl. Electrochem., 2010, vol. 40, p. 393.
  15. Aballe, A., Bethencourt, M., Botana, F.J., Marcos, M., and Osuna, R.M., Electrochemical noise applied to the study of the inhibition effect of CeCl3 on the corrosion behavior of Al–Mg alloy AA5083 in seawater, Electrochim. Acta, 2002, vol. 47, p. 1415.
  16. Garcia-Ochoa, E. and Genesca, J., Understanding the inhibiting properties of 3 amino-1,2,4-triazole from fractal analysis, Surf. Coat. Technol., 2004, vol. 184, p. 322.
  17. Grafov, B.M., Kluev, A.L., Kabanova, T.B., and Davydov, A.D., Chebyshev spectra resistance to trend of random noise, Fluctuation Noise Lett., 2018, vol. 17, 1850028.
  18. Grafov, B.M., Dobrovolskii, Yu.A., Klyuev, A.L., Ukshe, A.E., Davydov, A.D., and Astaf’ev, E.A., Median Chebyshev spectroscopy of electrochemical noise, J. Solid State Electrochem., 2017, vol. 21, p. 915.
  19. https://www.analog.com/en/design-center/evaluation-hardware-and-software/evaluation-boards-kits/eval-ad7176-2.html (29.11.2019).
  20. Orazem, M.E. and Tribollet, B., Electrochemical Impedance Spectroscopy,Wiley, 2008, p. 159.
  21. Kim, Y.S. and Kim, J.G., Electrochemical and quantum chemical studies of 1, 2, 3-benzotriazole as inhibitor for copper and steel in simulated tap water, Mater. Trans., 2017, vol. 58, p. 76.