Статья
2017

Electrosynthesis of Н2О2 from О2 in Gas Diffusion Electrodes Based on Black СН600

V. L. Kornienko V. L. Kornienko , G. A. Kolyagin G. A. Kolyagin , G. V. Kornienko G. V. Kornienko , V. A. Parfenov V. A. Parfenov , A. A. Petin A. A. Petin
Российский электрохимический журнал
https://doi.org/10.1134/S1023193517120059
Abstract / Full Text
Kornienko, V.L., Kolyagin, G.A., Kornienko, G.V. et al. Electrosynthesis of Н2О2 from О2 in Gas Diffusion Electrodes Based on Black СН600. Russ J Electrochem 53, 1307–1313 (2017). https://doi.org/10.1134/S1023193517120059

Furnace black СН600 was studied as a catalyst for electrosynthesis of Н2О2 from О2 in a gas diffusion electrode in alkaline and acidic solutions. The texture properties of the starting black СН600 and gas diffusion electrodes (GDEs) based on it were determined by the low-temperature nitrogen adsorption (LTNA) method. The rate constants of Н2О2 decomposition on black and its mixtures with fluoroplast-4D in acidic and alkaline solutions of electrolyte were calculated. The process selectivity γ (the current fraction spent on the two-electron reduction of oxygen), kinetic parameters of oxygen reduction, and double-layer capacity of the СН600-based GDE were determined. Data on the kinetics of hydrogen peroxide accumulation during electrosynthesis from oxygen in СН600-based GDE in acidic and alkaline solutions were obtained.

Author information

  • Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russia

    V. L. Kornienko, G. A. Kolyagin, G. V. Kornienko & V. A. Parfenov

  • Siberian State Technological University, Krasnoyarsk, 660049, Russia

    G. V. Kornienko

  • Scientific and Technological Center of Carbon Materials, Omsk, 644049, Russia

    A. A. Petin

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