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Статья
2017

Electrosynthesis of Н2О2 from О2 in Gas Diffusion Electrodes Based on Black СН600

V. L. KornienkoV. L. Kornienko, G. A. KolyaginG. A. Kolyagin, G. V. KornienkoG. V. Kornienko, V. A. ParfenovV. A. Parfenov, A. A. PetinA. A. Petin
Российский электрохимический журнал
https://doi.org/10.1134/S1023193517120059
Abstract / Full Text
Kornienko, V.L., Kolyagin, G.A., Kornienko, G.V. et al. Electrosynthesis of Н2О2 from О2 in Gas Diffusion Electrodes Based on Black СН600. Russ J Electrochem 53, 1307–1313 (2017). https://doi.org/10.1134/S1023193517120059

Furnace black СН600 was studied as a catalyst for electrosynthesis of Н2О2 from О2 in a gas diffusion electrode in alkaline and acidic solutions. The texture properties of the starting black СН600 and gas diffusion electrodes (GDEs) based on it were determined by the low-temperature nitrogen adsorption (LTNA) method. The rate constants of Н2О2 decomposition on black and its mixtures with fluoroplast-4D in acidic and alkaline solutions of electrolyte were calculated. The process selectivity γ (the current fraction spent on the two-electron reduction of oxygen), kinetic parameters of oxygen reduction, and double-layer capacity of the СН600-based GDE were determined. Data on the kinetics of hydrogen peroxide accumulation during electrosynthesis from oxygen in СН600-based GDE in acidic and alkaline solutions were obtained.

Author information

  • Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russia

    V. L. Kornienko, G. A. Kolyagin, G. V. Kornienko & V. A. Parfenov

  • Siberian State Technological University, Krasnoyarsk, 660049, Russia

    G. V. Kornienko

  • Scientific and Technological Center of Carbon Materials, Omsk, 644049, Russia

    A. A. Petin

References
  1. Chizmadzhev, Yu.A., Markin, V.S., Tarasevich, M.R., and Chirkov, Yu.G., Makrokinetika protsessov v poristykh sredakh (Toplivnye elementy) (Macrokinetics of Processes in Porous Media (Fuel Cells)), Moscow: Nauka, 1971.
  2. Kornienko, V.L., Kolyagin, G.A., and Saltykov, Yu.V., Elektrosintez v gidrofobizirovannykh elektrodakh (Electrosynthesis in Waterproofed Electrodes), Tomilov, A.P., Ed., Novosibirsk: Siberian Branch, Russian Academy of Sciences, 2011.
  3. Anastas, P.T. and Warner, J.C., Green Chemistry: Theory and Practice, London: Oxford University Press, 1998.
  4. Noyori, R., Chem. Commun., 2005, vol. 14, p. 1807.
  5. Khimiya i tekhnologiya perekisi vodoroda (Chemistry and Technology of Hydrogen Peroxide), Seryshev, G.A., Ed., Leningrad: Khimiya, 1984.
  6. Pletcher, D., Acta Chem. Scand., 1999, vol. 53, p. 745.
  7. Kornienko, V.L., Kolyagin, G.A., and Saltykov, Yu.V., Zh. Prikl. Khim., 1999, vol. 72, p. 353.
  8. Kolyagin, G.A. and Kornienko, V.L., Zh. Prikl. Khim., 2003, vol. 76, p. 1103.
  9. Kolyagin, G.A. and Kornienko, V.L., Elektrosintez peroksida vodoroda v gazodiffuzionnom elektrode. Dostizheniya i perspektivy (Electrosynthesis of Hydrogen Peroxide in a Gas Diffusion Electrode: Achievements and Prospects), LAP Lambert, 2011.
  10. Duke, F.R. and Haas, T.W., J. Phys. Chem., 1961, vol. 65, p. 304.
  11. Elektrokhimiya organicheskikh soedinenii v nachale XXI veka (Electrochemistry of Organic Compounds in the Early 21st Century), Gul’tyai, V.P., Krivenko, A.G., and Tomilov, A.P., Eds., Moscow: Kompaniya Sputnik+, 2008.
  12. Kenova, T.A., Kornienko, V.L., and Drozdov, S.V., Zh. Prikl. Khim., 2010, vol. 83, p. 1489.
  13. Brillas, E., Mur, E., and Casado, I., J. Electrochem. Soc., 1996, vol. 143, p. 49.
  14. Brillas, E., Sauleda, R., and Casado, I., J. Electrochem. Soc., 1997, vol. 144, p. 2374.
  15. Chaenko, N.V., Kornienko, V.L., and Selyutin, G.E., Zh. Prikl. Khim., 1996, vol. 69, p. 1988.
  16. Chaenko, N.V., Kornienko, G.V., Pustovalova, T.L., and Kornienko, V.L., Zh. Prikl. Khim., 1991, vol. 64, p. 2297.
  17. Chaenko, N.V., Kornienko, V.L., Turenko, L.G., and Pustovalova, T.L., Zh. Prikl. Khim., 1989, vol. 62, p. 57.
  18. Kornienko, G.V., Kolyagin, G.A., Kornienko, V.L., and Parfenov, V.A., Russ. J. Electrochem., 2016, vol. 52, p. 983.
  19. Razd’yakonova, G.I., Likholobov, V.A., Moiseevskaya, G.V., Petin, A.A., and Karaev, M.Yu., Innovatsionnyi uglerod. Ot idei do tekhnologii (Innovative Carbon: From Idea to Technology), Omsk: Omsk. Gos. Tekh. Univ., 2014.
  20. Zakharkin, G.P., Tarasevich, M.R., and Burshtein, R.Kh., Elektrokhimiya, 1974, vol. 10, p. 1811.
  21. Kolyagin, G.A. and Kornienko, V.L., Russ. J. Appl. Chem., 2008, vol. 81, p. 423.
  22. Kolyagin, G.A. and Kornienko, V.L., Russ. J. Electrochem., 2016, vol. 52, p. 185.
  23. Tarasevich, M.R., Sabirov, F.Z., and Burshtein, R.Kh., Elektrokhimiya, 1971, vol. 7, p. 404.
  24. Alekseev, V.I., Kolichestvennyi analiz (Quantitative Analysis), Moscow: Khimiya, 1972.
  25. Tarasevich, M.R., Beketaeva, L.A., Efremov, B.N., Zagudaeva, N.M., Kuznetsova, L.N., Rybalka, K.V., and Sosenkin, V.E., Russ. J. Electrochem., 2004, vol. 40, p. 542.