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Статья
2021

Investigation of Hydrogen Evolution Reaction on (TiCr1.8)xV100 – x Alloys via Impedance Spectroscopy Method


A. A. MironovaA. A. Mironova, N. A. MedvedevaN. A. Medvedeva, V. I. KichiginV. I. Kichigin, N. E. SkryabinaN. E. Skryabina, D. FruchartD. Fruchart
Российский электрохимический журнал
https://doi.org/10.1134/S1023193521080085
Abstract / Full Text

Abstract

The behavior of the (TiCr1.8)xV100 – x intermetallic system in the reaction of hydrogen evolution in 1 M KOH solution has been studied by polarization measurements and electrochemical impedance spectroscopy. Cathodic polarization curves and impedance spectra were obtained in the potential range corresponding to the linear region of the log iE dependence. All investigated alloys have two linear sections on the cathodic polarization curves. The two sections of the potential dependence are also revealed in other electrochemical parameters of the system. Impedance spectroscopy allowed establishing that no thick oxide film is present on the alloys’ surfaces. For the analysis of the obtained impedance spectra, three equivalent electrical circuits were applied, in order to describe the electrochemical hydrogen evolution. The parameters of the Faraday impedance were calculated. Assumptions about the hydrogen evolution reaction behavior according to the Volmer–Heyrovsky mechanism and Temkin adsorption isotherm were made.

Author information
  • Perm State University, Perm, RussiaA. A. Mironova, N. A. Medvedeva, V. I. Kichigin & N. E. Skryabina
  • Institut Néel, CNRS, Grenoble, FranceD. Fruchart
References
  1. Anik, M., Akay, I., Ozdemir, G., and Baksan, B., Electrochemical hydrogen storage performance of Mg–Ti–Zr–Ni alloys, Int. J. Hydrogen Energy, 2009, vol. 34, p. 9765.
  2. Balcerzak, M., Structure and hydrogen storage properties of mechanically alloyed Ti–V alloys, Int. J. Hydrogen Energy, 2017, vol. 42, no. 37, p. 23698.
  3. Pebler, A. and Gulbransen, E.A., Thermochemical and structural aspects of the reaction of hydrogen with alloys and intermetallic compounds of zirconium, Electrochem. Technol., 1966, vol. 4, p. 211.
  4. Shaltiel, A.D., Jacob, I., and Davidov, D., Hydrogen absorption and desorption properties of AB2 laves-phase pseudobinary compounds, J. Less Common Met., 1977, vol. 53, no. 1, p. 117.
  5. Johnson, J.R. and Reilly, J.J., Reaction of hydrogen with the low-temperature form (C15) of titanium-chromium (TiCr2), Inor. Chem., 1978, vol. 17, no. 11, p. 3103.
  6. Johnson, J.R., Reaction of hydrogen with the high temperature (C14) form of TiCr2, J. Less Common Met., 1980, vol. 73, no. 2, p. 345.
  7. Skryabina, N.E. et al, Correlation between the Hydrogen Absorption Properties and the Vanadium Concentration of Ti-V-Cr Based Alloy, Solid State Phenomena, 2017, vol. 257, p.165.
  8. Tamura, T., Kazumi, T., Kamegawa, A., Takamura, H., and Okada, M., Protium absorption properties and protide formations of Ti–Cr–V alloys, J. Alloys. Compd., 2003, vol. 356, p. 505.
  9. Cho, S.-W., Han, Ch.-S., Park, Ch.-N., and Akiba, E., The hydrogen storage characteristics of Ti–Cr–V alloys, J. Alloys Comp., 1999, vol. 288, p. 294.
  10. Huang, T., Wu, Z., Xia, B., and Huang, T., Influence of V content on structure and hydrogen desorption performance of TiCrV-based hydrogen storage alloys, Mater. Chem. and Phys., 2005, vol. 93, p. 544.
  11. Akiba, E. and Iba, H., Hydrogen absorption by Laves phase related BCC solid solution, Intermetallics, 1998, vol. 6, p. 461.
  12. Iba, H. and Akiba, E., Hydrogen absorption and modulated structure in Ti–V–Mn alloys, J. Alloys Comp., 1997, vol. 253–254, p. 21.
  13. Seo, C., Kim, J., Lee, P.S., and Lee, J., Hydrogen storage properties of vanadium-based b.c.c. solid solution metal hydrides, J. Alloys Comp., 2003, vol. 348, p. 252.
  14. Vigdorovich, V.I., Tsygankova, L.E., Zarapina, I.V., Shel, N.V., and Matveyeva, M.V., Some questions of the reaction of hydrogen evolution and its diffusion through a steel membrane, News of Higher Schools. Chem. and Chem. Technol., 2006, vol. 49, no. 11, p. 86.
  15. Lasia, A., Electrochemical Impedance Spectroscopy and Its Applications, New York: Springer, 2014.
  16. Kuleshov, V.N., Korovin, N.V., Kuleshov, N.V., Udris, E.Ya., and Bakhin, A.N., Development of new electrocatalysts for low-temperature electrolysis of water, Electrohem. Energetika (in Russian), 2012, vol. 12, no. 2, p. 51.
  17. Antropov, L.I., Theoretical Electrochemistry, Univ. Press of the Pacific, 2001.
  18. Wilhelmsen, W. and Grande, A.P., Electrochemical and SIMS studies of cathodically formed hydride layers on titanium, Electrochim. Acta, 1990, vol. 35, no. 11–12, p. 1913.
  19. Yakimenko, L.M., Modylevskaya, I.D., and Tkachek, Z.A., Electrolysis of Water (in Russian), Moscow: Khimiya, 1970.
  20. Gabov, A.L., Medvedeva, N.A., Skryabina, N.E., and Fruchart, D., Sorption capacity of alloys of the (TiCr1.8)1 – xVx system under conditions of electrolytic saturation with hydrogen, Chem. Sustainable Development, 2014, vol. 22, p. 509.
  21. Arashima, H., Takahashi, F., Ebisawa, T., Itoh, H., and Kabutomori, T., Correlation between hydrogen absorption properties and homogeneity of Ti–Cr–V alloys, J. Alloys Comp., 2003, vol. 356–357, P. 405.
  22. Kichigin, V.I., Shein, A.B., and Shamsutdinov, A.Sh., Kinetics of cathodic hydrogen evolution on iron monosilicide in acidic and alkaline media, Kondensirovannye sredy mezhfaznye granitsy, 2016, vol. 18, no. 3, p. 326.
  23. Kichigin, V.I., Shein, A.B., and Shamsutdinov, A.Sh., Kinetics of hydrogen evolution reaction on nickel monosilicide in acidic and alkaline solutions, Kondensirovannye sredy mezhfaznye granitsy, 2017, vol. 19, no. 2, p. 222.
  24. Lim, C. and Pyun, S.I., Theoretical approach to faradaic admittance of hydrogen absorption reaction on metal membrane electrode, Electrochim. Acta, 1993, vol. 38, no. 18, p. 2645.
  25. Harrington, D.A. and Conway, B.E., AC Impedance of Faradaic reactions involving electrosorbed intermediates. I. Kinetic theory, Electrochim. Acta, 1987, vol. 32, no. 12, p. 1703.
  26. Kichigin, V.I. and Shein, A.B., Diagnostic criteria for hydrogen evolution mechanisms in electrochemical impedance spectroscopy, Electrochim. Acta, 2014, vol. 138, p. 325.
  27. Martin, M.H. and Lasia, A., Hydrogen sorption in Pd monolayers in alkaline solution, Electrochim. Acta, 2009, vol. 54, p. 5292.
  28. Kichigin, V.I. and Shein, A.B., Influence of hydrogen absorption on the potential dependence of the Faradaic impedance parameters of hydrogen evolution reaction, Electrochim. Acta, 2016, vol. 201, p. 233.
  29. Lasia, A., On the mechanism of the hydrogen absorption reaction, J. Electroanal. Chem., 2006, vol. 593, no. 1–2, p. 159.
  30. Łosiewicz, B., Birry, L., and Lasia, A., Effect of adsorbed carbon monoxide on the kinetics of hydrogen electrosorption into palladium, J. Electroanal. Chem., 2007, vol. 611, no. 1–2, p. 226.