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Статья
2022

Photoinduced Absorption Spectra of Donor–Acceptor Systems Based on Cobalt(II) and Manganese(III) Phthalocyanine Complexes with Femtosecond Time Resolution


E. N. OvchenkovaE. N. Ovchenkova, N. G. BichanN. G. Bichan, T. N. LomovaT. N. Lomova
Российский журнал физической химии А
https://doi.org/10.1134/S0036024422040240
Abstract / Full Text

Results of studying the ultrafast dynamics of excited states of cobalt(II) and manganese(III) octakis(3,5-di-tert-butylphenoxy)phthalocyanines, along with donor–acceptor systems based on them with fullero[60]- and fullero[70]pyrrolidines as acceptors are represented. Excited states are achieved by exposing the absorbing substances to laser pulses in femtosecond absorption spectroscopy. The kinetics and types of photoinduced absorption spectra of metal phthalocyanines and their dyads with substituted pyrrolidines are described, along with the lifetimes of states with separated charges. The corresponding constants of charge separation and recombination are determined.

Author information
  • Krestov Institute of Chemistry of Solutions, Russian Academy of Sciences, 153045, Ivanovo, RussiaE. N. Ovchenkova, N. G. Bichan & T. N. Lomova
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