N-Substituted-3-aminopropylsilsesquioxanes: synthesis, physicochemical properties, and application
M. E. Evseev, A. S. Kholmogorova, L. K. Neudachina, A. V. Pestov, I. S. Puzyrev, V. A. Osipova, L. V. Adamova
Российский химический вестник
https://doi.org/10.1007/s11172-021-3198-z
Synthesis and study of the physicochemical properties of silsesquioxanes modified with 3-aminopropyl, 2-aminoethyl-3-aminopropyl, and dithiooxamide groups was carried out. The obtained sorbents were characterized by thermal stability, porosity, and a high degree of functionalization; the concentration of groups grafted to the particle surface reached 2.80 mmol g−1. Modified silsesquioxanes were used as an electroactive substance for the development of indicator carbon paste electrodes (CPEs). When using a CPE with a 5% dithiooxamidated silsesquioxane content, the conditions selected for potentiometric titration of aqueous solutions containing silveri were pH 3–4, the titrant was potassium iodide. The designed sensor was successfully tested by analyzing a standard sample and a drug for silver ion content.
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