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Статья
2021

N-Substituted-3-aminopropylsilsesquioxanes: synthesis, physicochemical properties, and application


M. E. EvseevM. E. Evseev, A. S. KholmogorovaA. S. Kholmogorova, L. K. NeudachinaL. K. Neudachina, A. V. PestovA. V. Pestov, I. S. PuzyrevI. S. Puzyrev, V. A. OsipovaV. A. Osipova, L. V. AdamovaL. V. Adamova
Российский химический вестник
https://doi.org/10.1007/s11172-021-3198-z
Abstract / Full Text

Synthesis and study of the physicochemical properties of silsesquioxanes modified with 3-aminopropyl, 2-aminoethyl-3-aminopropyl, and dithiooxamide groups was carried out. The obtained sorbents were characterized by thermal stability, porosity, and a high degree of functionalization; the concentration of groups grafted to the particle surface reached 2.80 mmol g−1. Modified silsesquioxanes were used as an electroactive substance for the development of indicator carbon paste electrodes (CPEs). When using a CPE with a 5% dithiooxamidated silsesquioxane content, the conditions selected for potentiometric titration of aqueous solutions containing silveri were pH 3–4, the titrant was potassium iodide. The designed sensor was successfully tested by analyzing a standard sample and a drug for silver ion content.

Author information
  • Ural Federal University named after the first President of Russia B. N. Yeltsin, 19 ul. Mira, 620002, Ekaterinburg, Russian FederationM. E. Evseev, A. S. Kholmogorova, L. K. Neudachina, A. V. Pestov & L. V. Adamova
  • I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22/20 ul. S. Kovalevskoi, 620108, Ekaterinburg, Russian FederationA. V. Pestov, I. S. Puzyrev & V. A. Osipova
References
  1. T. S. Lubova, I. D. Grishin, N. S. Zaharycheva, E. A. Zaharychev, S. A. Lermontova, L. G. Klapshina, E. Yu. Ladilina, Russ. Chem. Bull., 2021, 70, 99.
  2. O. V. Baranov, L. G. Komarova, S. S. Golubkov, Russ. Chem. Bull., 2020, 69, 1165; DOI: https://doi.org/10.1007/s11172-020-2884-6.
  3. A. A. Anisimov, A. V. Arzumanyan, A. V. Bystrova, N. G. Vasilenko, M. O. Gallyamov, E. V. Egorova, A. B. Zachernyuk, A. A. Kalinina, Yu. N. Kononevich, V. M. Kotov, I. B. Meshkov, S. A. Milenin, Yu. A. Molodtsova, A. M. Muzafarov, A. N. Tarasenkov, M. N. Temnikov, D. I. Shragin, I. V. Elmanovich, Beskhloraya khimiya silikonov — doroga v budushchee [Chlorine-free Chemistry of Silicones — the Road to the Future], ed. A. M. Muzafarov, Pero, Moscow, 2018, 308 pp. (in Russian).
  4. Q. Wei, C. Lian, H. Su, D Gao, S. Wang, Micropor. Mesopor. Mater., 2019, 288, 1387; DOI: https://doi.org/10.1016/j.micromeso.2019.109574.
  5. L. González, S. Morante-Zarcero, D. Pérez-Quintanilla, I. Sierra, J. Chromatogr. A, 2020, 1622, 461124; DOI: https://doi.org/10.1016/j.chroma.2020.461124.
  6. J. Gañán, S. Morante-Zarcero, D. Pérez-Quintanilla, I. Sierra, Microchem. J., 2020, 157, 104877; DOI: https://doi.org/10.1016/j.microc.2020.104877.
  7. A. Walcarius, Electroanalysis, 2001, 13, 701; DOI: https://doi.org/10.1002/1521-4109(200105)13:8/9<701:AID-ELAN701>3.0.CO;2-6.
  8. A. Walcarius, Chem. Soc. Rev., 2013, 42, 4098; DOI: https://doi.org/10.1039/C2CS35322A.
  9. E. S. Farrell, Y. Schlit, M. Y. Moshkovitz, Y. Levi-Kalisman, U. Raviv, S. Magdassi, Nano Lett., 2020, 20, 6598; DOI: https://doi.org/10.1021/acs.nanolett.0c023646.
  10. S. Yismaw, S. G. Ebbinghaus, M. Wenzel, D. Poppitz, R. Gläser, J. Matysik, F. Bauer, D. Enke, J. Nanoparticle Res., 2020, 22, 279; DOI: https://doi.org/10.1007/s11051-020-05006-2.
  11. M. Turkawka, K. Cendrowski, W. Konicki, E. Mijowska, Appl. Sci., 2020, 10, 6465; DOI: https://doi.org/10.3390/APP10186465.
  12. B. W. Sands, Y. S. Kim, J. L. Bass, J. Chromatogr. A, 1985, 360, 353; DOI: https://doi.org/10.1016/S0021-9673(00)91685-6.
  13. K. Gdula, A. Gładysz-Płaska, B. Cristóvão, W. Ferenc, E. Skwarek, J. Mol. Liq., 2019, 290, 111217; DOI: https://doi.org/10.1016/j.molliq.2019.111217.
  14. M. Li, T. Wang, J. Zhang, Mater. Res. Express., 2019, 6, 1150C2; DOI: https://doi.org/10.1088/2053-1591/ab4d6a.
  15. N. Casado, D. Pérez-Quintanilla, S. Morante-Zarcero, I. Sierra, Trends Anal. Chem., 2017, 88, 167; DOI: https://doi.org/10.1016/j.trac.2017.01.001.
  16. T. N. Nefedova, F. Resner, V. F. Selemenev, Sorption Chromatogr. Proces., 2020, 20, 31; DOI: https://doi.org/10.17308/sorpchrom.2020.20/2377.
  17. V. V. Sliesarenko, O. A. Dudarko, A. K. Matkovskii, G. R. Yurchenko, Yu. L. Zub, Colloid J., 2014, 76, 366; DOI: https://doi.org/10.1134/S1061933X14020124.
  18. O. A. Dudarko, C. Gunathilake, N. P. Wickramaratne, V. V. Sliesarenko, Yu. L. Zub, J. Górka, S. Dai, M. Jaroniec, Colloids Surfaces A, 2015, 482, 1; DOI: https://doi.org/10.1016/j.colsurfa.2015.04.016.
  19. M. A. Ahmed, A. A. Abu Shaweesh, N. M. El-Agshar, I. M. El-Nahhal, M. M. Chehimi, F. Babonneau, J. Sol-Gel Sci. Technol., 2016, 78, 660; DOI: https://doi.org/10.1007/s10971-016-3980-9.
  20. A. Avanes, M. Hasanzadeh-Karamjavan, G. Shokri-Jarcheloo, Microchim. Acta, 2019, 186, 441; DOI: https://doi.org/10.1007/s00604-019-3555-x.
  21. S. Jahandari, M. A. Taher, H. Fazelirad, I. Sheikhshoai, Microchim. Acta, 2013, 180, 347; DOI: https://doi.org/10.1007/s00604-012-0935-x.
  22. A. S. Kholmogorova, E. A. Fedoseeva, L. K. Neudachina, V. A. Osipova, A. V. Pestov, J. Appl. Chem., 2021, 94, 482.
  23. L. K. Neudachina, A. S. Kholmogorova, I. S. Puzyrev, Z. R. Galieva, Russ. J. Phys. Chem., 2018, 92, 2309; DOI: https://doi.org/10.1134/S0036024418110304.
  24. A. R. Cestari, E. F. S. Vieira, R. E. Bruns, C. Airoldi, J. Colloid Interface Sci., 2000, 227, 66; DOI: https://doi.org/10.1006/jcis.2000.6841.
  25. A. R. Cestari, E. F. S. Vieira, J. A. Simoni, C. Airoldi, Thermochim. Acta, 2000, 348, 25; DOI: https://doi.org/10.1016/s0040-6031(99)00380-9.
  26. L. N. H. Arakaki, C. Airoldi, Polyhedron, 2000, 19, 367; DOI: https://doi.org/10.1016/S0277-5387(99)00347-2.
  27. I. S. Puzyrev, A. S. Kholmogorova, L. K. Neudachina, A. V. Mekhaev, A. V. Pestov, Russ. J. Appl. Chem. A, 2014, 87, 715; DOI: https://doi.org/10.1134/S1070427214060081.
  28. E. M. Sokolovskaya, L. S. Guzei, in General Chemistry, Eds E. M. Sokolovskaya, L. S. Guzei, Moscow University Press, Moscow, 1989, p. 188.
  29. L. K. Neudachina, A. Ya. Golub, Yu. G. Yatluk, V. A. Osipova, Yu. A. Berdyugin, E. M. Gorbunova, L. V. Adamova, O. V. Koryakova, M. V. Kuznetsov, Inorg. Mater., 2011, 47, 435; DOI: https://doi.org/10.1134/S0020168511030174