Ionic mobility and electrophysical properties of solid solutions in PbF2–SbF3 and PbF2–SnF2–SbF3 systems

V. Ya. Kavun V. Ya. Kavun , N. F. Uvarov N. F. Uvarov , A. B. Slobodyuk A. B. Slobodyuk , A. S. Ulikhin A. S. Ulikhin , I. A. Telin I. A. Telin , V. K. Goncharuk V. K. Goncharuk
Российский электрохимический журнал
Abstract / Full Text

Ionic mobility and electrical conductivity of solid solutions with fluorite structure, obtained with solid-state approach in PbF2–SbF3 and PbF2–SnF2–SbF3 systems, are studied by 19F NMR and electrochemical impedance spectroscopy methods. The 19F NMR spectra parameters, types of ion motions in the fluoride sublattice, and the ionic conductivity magnitude are shown to be determined by the temperature and fluoride concentration in the solid solutions. The solid solution specific conductivity in the PbF2–SbF3 and PbF2–SnF2–SbF3 systems at 420–450 K is as high as ~10–2 S/cm, which allows accounting the solid solutions as a base for preparation of functional materials.

Author information
  • Institute of Chemistry, Far East Branch, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    V. Ya. Kavun, A. B. Slobodyuk, I. A. Telin & V. K. Goncharuk

  • Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, ul. Kutateladze 18, Novosibirsk, 630128, Russia

    N. F. Uvarov & A. S. Ulikhin

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