Статья
2000

Lead adatoms on submonolayers of selenium and tellurium deposited on a gold electrode

N. P. Osipovich N. P. Osipovich , E. A. Strel’tsov E. A. Strel’tsov
Российский электрохимический журнал
https://doi.org/10.1007/BF02757787
Abstract / Full Text
Osipovich, N.P., Strel’tsov, E.A. Lead adatoms on submonolayers of selenium and tellurium deposited on a gold electrode. Russ J Electrochem 36, 1–7 (2000). https://doi.org/10.1007/BF02757787

Electrochemical adsorption-desorption of lead atoms (Pbad) on a gold electrode covered by submonolayers of selenium and tellurium (Au/Sead, Au/Tead) is studied at potentials exceeding the equilibrium potential of the Pb(II)-Pb(0) system. Cyclic voltammetry reveals that energy states of lead adatoms depend on the presence of submonolayer or supermonolayer amounts of a chalcogen. The underpotential deposition of lead adatoms on Au/Sead and Au/Tead is irreversible, which is due to the formation of chemical bonds Pb-Se and Pb-Te. Electrochemical adsorption of lead atoms on Au/Sead and Au/Tead leads to the formation of submonolayers of lead chalcogenides Au/PhSead and Au/PhTead. Stability of submonolayer structures of Au/Sead, Au/Tead, Au/PbSead, and Au/PbTead is studied under open-circuit conditions. The structures have rather long storage times (dozens of minutes) in aqueous acid solutions of HNO3 saturated with argon.

Author information

  • Research Institute of Physicochemical Problems, Belarussian State University, ul. Leningradskaya 14, 220080, Minsk, Belarus

    N. P. Osipovich & E. A. Strel’tsov

References
  1. Kolb, D.M.,Advances in Electrochemistry and Electrochemical Engineering, Genscher, H. and Tobias, C.W., Eds., New York: Wiley, 1978, vol. 11, p. 125.
  2. Jüttner, K. and Lorenz, W.J.,Z. Phys. Chem. (Leipzig), 1980, vol. 122, p. 163.
  3. Conway, B.E.,Progr. Surf. Sci., 1984, vol. 16, p. 1.
  4. Kolb, D.M.,Ber. Bunsen-Ges. Phys. Chem., 1988, vol. 92, p. 1175.
  5. Petrii, O.A. and Lapa, A.S.,Itogi Nauki Tekh., Ser: Elektrokhimiya, 1987, vol. 24, p. 94.
  6. Danilov, A.I., Molodkina, E.V., and Polukarov, Yu.M.,Elektrokhimiya, 1994, vol. 30, p. 748.
  7. Danilov, A.I.,Usp. Khim., 1995, vol. 64, p. 818.
  8. Danilov, A.I., Molodkina, E.V., and Polukarov, Yu.M.,Elektrokhimiya, 1997, vol. 33, p. 313.
  9. Danilov, A.I., Molodkina, E.V., and Polukarov, Yu.M.,Elektrokhimiya, 1997, vol. 33, p. 320.
  10. Lucas, CA., Markovic, N.M., and Ross, P.N.,Phys. Rev. B: Condens. Matter, 1998, vol. 57, p. 13184.
  11. Yee, H.S. and Abruna, H.D.,Langmuir, 1993, vol. 9, p. 2460.
  12. Sackmann, J., Bunk, A., Potzchke, R.T.,et al., Electrochim. Acta, 1998, vol. 43, p. 2863.
  13. Adzic, R.R. and Despic, A.R.,J. Phys. Chem., 1974, vol. 61, p. 3482.
  14. Adzic, R.R., Despic, A.R., Simic, D.N., and Drazic, D.M.,U. S. Nat. Bur. Stand. Spec. Publ, 1975, no. 455, p. 191.
  15. Han-Wei, L., Hattori, H., and Kita, H.,Electrochim. Acta, 1996, vol. 41, p. 1619.
  16. Abe, T., Swain, G.M., Sashikata, K., and Itaya, K.,J. Electroanal. Chem., 1995, vol. 382, p. 73.
  17. Herrero, E., Llorca, M.J., Feliu, J.M., and Aldaz, A.,J. Electroanal. Chem., 1995, vol. 383, p. 145.
  18. Jüttner, K.,Electrochim. Acta, 1984, vol. 29, p. 1597.
  19. Markovic, N.M., Gasteiger H.A., and Ross, P.N.,Langmuir, 1995, vol. 11, p. 4098.
  20. Michaelis, R., Zei, M.S., Zhai, R.S., and Kolb, D.M.,J. Electroanal. Chem, 1992, vol. 339, p. 299.
  21. Scortichini, C.L. and Reilley, C.,J. Electroanal. Chem., 1982, vol. 139, p. 247.
  22. Brainina, Kh.Z. and Nikiforov, V.V.,Elektrokhimiya, 1989, vol. 25, p. 1237.
  23. Gregory, B.W. and Stickney, J.L.,J. Electroanal. Chem., 1991, vol. 300, p. 543.
  24. Gregory, B.W., Suggs, D.W., and Stickney, J.L.,J. Electrochem. Soc, 1991, vol. 138, p. 1279.
  25. Huang, B.M., Colletti, L.P., Gregory, B.W.,et al., J. Electrochem. Soc, 1995, vol. 142, p. 3007.
  26. Goetting, L.B., Huang, B.M., Lister, T.E., and Stickney, J.L.,Electrochim. Acta, 1995, vol. 40, p. 143.
  27. Colletti, L.P., Flowers, B.H., and Stickney, J.L.,J. Electrochem. Soc, 1998, vol. 145, p. 1442.
  28. Colletti, L.P. and Stickney, J.L.,J. Electrochem. Soc, 1998, vol. 145, p. 3594.
  29. Strel’tsov, E.A., Labarevich, I.I., and Talapin, D.V.,Dokl. Akad. Nauk Belarusi, 1994, vol. 38, p. 64.
  30. Demir, U. and Shannon, C.,Langmuir, 1994, vol. 10, p. 2794.
  31. Boone, B.E. and Shannon, C.,J. Phys. Chem., 1996, vol. 100, p. 9480.
  32. Demir, U. and Shannon, C.,Langmuir, 1996, vol. 12, p. 594.
  33. Demir, U. and Shannon, C.,Langmuir, 1996, vol. 12, p. 6091.
  34. Strel’tsov, E.A., Osipovich, N.P., Ivashkevich, L.S., and Lyakhov, A.S.,Dokl. Akad. Nauk Belarusi, 1997, vol. 41, p. 69.
  35. Strel’tsov, E.A., Osipovich, N.P., Ivashkevich, L.S.,et al., Zh. Prikl. Khim. (Leningrad), 1997, vol. 70, p. 1735.
  36. Strel’tsov, E.A., Osipovich, N.P., Ivashkevich, L.S., and Lyakhov, A.S.,Dokl. Akad. Nauk Belarusi, 1997, vol. 41, p. 65.
  37. Streltsov, E.A., Osipovich, N.P., Ivashkevich, L.S.,et al., Electrochim. Acta, 1998, vol. 43, p. 869.
  38. Streltsov, E.A., Osipovich, N.P., Ivashkevich, L.S., and Lyakhov, A.S.,Electrochim. Acta, 1998, vol. 44, p. 407.
  39. Streltsov, E.A., Osipovich, N.P., Ivashkevich, L.S., and Lyakhov, A.S.,Electrochim. Acta, 1999, vol. 45.
  40. Trassati, S. and Petrii, O.A.,Elektrokhimiya, 1993, vol. 29, p. 557.
  41. Gregory, B.W., Norton, M.L., and Stickney, J.L.,J. Electroanal. Chem., 1990, vol. 293, p. 85.
  42. Suggs, D.W. and Stickney, J.L.,J. Phys. Chem., 1991, vol. 95, p. 10056.
  43. Andrews, R.W. and Johnson, D.C.,Anal. Chem., 1975, vol. 47, p. 294.
  44. Lister, T.E. and Stickney, J.L.,J. Electroanal. Chem., 1976, vol. 100, p. 568.
  45. Takamura, T., Takamura, K., Nippe, W., and Yeager, E.,J. Electrochem. Soc, 1970, vol. 117, p. 626.
  46. Takamura, T., Sato, Y., and Takamura, K.,J. Electroanal. Chem., 1973, vol. 41, p. 31.
  47. Vicente, V.A. and Bruckenstein, S.,Anal. Chem., 1973, vol. 45, p. 2036.
  48. Adzic, R., Yeager, E., and Cahan, B.D.,J. Electrochem. Soc, 1974, vol. 121, p. 474.
  49. Lorenz, W.J., Hermann, H.D., Wüthrich, N., and Hubert, F.,J. Electrochem. Soc, 1974, vol. 121, p. 1167.
  50. Hamelin, A. and Katayama, A.,J. Electroanal Chem., 1981, vol. 117, p. 221.
  51. Hepel, M., Kanige, K., and Bruckenstein, S.,Langmuir, 1990, vol. 6, p. 1063.
  52. Green, M.P., Hanson, K.J., Scherson, D.A.,et al., J. Phys. Chem., 1989, vol. 93, p. 2181.
  53. Conway, B.E. and Chacha, J.S.,J. Electroanal. Chem., 1990, vol. 287, p. 13.
  54. Binggeli, M., Carnal, D., Nyffenegger, R.,et al., J. Vac. Sci. Technol, 1991, vol. B9, p. 1985.
  55. Chen, C., Washburn, N., and Gewirth, A.,J. Phys. Chem., 1993, vol. 97, p. 9754.
  56. Brunt, A., Rayment, T., O’Shea, S.J., and Weiland, M.E.,Langmuir, 1996, vol. 12, p. 5942.