Статья
2020
Selective Liquid Phase Hydrogenation of Aromatic Nitro Compounds in the Presence of Fe–Cu Nanoparticles
A. A. Shesterkina, A. A. Strekalova, L. M. Kustov
Российский журнал физической химии А
https://doi.org/10.1134/S0036024420060217
Abstract / Full Text
Fe–Cu bimetallic oxide nanoparticles supported on silica gel that catalyze the hydrogenation of nitrobenzene to aniline and of dinitrobenzenes to phenylenediamines under relatively mild reaction conditions (200°C, \({{p}_{{{{{\text{H}}}_{2}}}}}\) 1.3 MPa, 4 h, and 700 rpm) are synthesized. The catalytic properties of supported bimetallic Fe–Cu catalysts depend on the synthesis procedure, sample composition, and conditions of thermal treatment. There is a synergistic effect of interaction between Cu and Fe in the hydrogenation of nitrobenzene, 1,3-dinitrobenzene, and 1,4-dinitrobenzene in the presence of a bimetallic Fe–Cu catalyst obtained via coprecipitation.
Author information
- Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119334, Moscow, RussiaA. A. Shesterkina, A. A. Strekalova & L. M. Kustov
- National University of Science and Technology (MISIS), 119049, Moscow, RussiaA. A. Shesterkina, A. A. Strekalova & L. M. Kustov
- Department of Chemistry, Moscow State University, 119991, Moscow, RussiaL. M. Kustov
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