Electrosynthesis of 1-Vinylimidazole- and Acrylic-Acid-Based Metal-Containing Nanocomposites

S. H. Sargsyan S. H. Sargsyan , T. S. Sargsyan T. S. Sargsyan , K. M. Khizantsyan K. M. Khizantsyan , I. G. Aghajanyan I. G. Aghajanyan , A. S. Sargsyan A. S. Sargsyan , K. S. Margaryan K. S. Margaryan
Российский электрохимический журнал
Abstract / Full Text

The possibility of electrochemical synthesis of nanocomposites and nanocomposite films at pure-iron and steel electrodes using a 1-vinylimidazole–acrylic-acid co-polymer in the presence of chitosan is shown. Using UV- and IR-spectroscopy, XRD- and elemental analyses, the nanocomposite’s structure and composition were elucidated. The nanocomposite solubility was shown to be determined by intramolecular interaction of macromolecules in the 1-vinylimidazole–acrylic-acid co-polymer with gold nanoparticles. The nanocomposite thermal decomposition is a multistage process.

Author information
  • National Polytechnic University of Armenia, 0009, Yerevan, Armenia

    S. H. Sargsyan, K. M. Khizantsyan & I. G. Aghajanyan

  • Yerevan State Medical University after Mkhitar Heratsi, 0025, Yerevan, Armenia

    T. S. Sargsyan, A. S. Sargsyan & K. S. Margaryan

  1. Pomogaylo, A.D., Rosenberg, A.S., and Uflyand, I.E., Metal Nanoparticles in Polymers (in Russian), Moscow: Khimiya, 2000.
  2. Holze, R. and Wu, Y.P., Electrochemistry of electroactive materials, Electrochim. Acta, 2014, vol. 122, p. 93.
  3. Rao, C.N.R., Muller, A., and Cheetham, A.K., The Chemistry of Nanomaterids, Weinheim: Wiley–WCH, 2004.
  4. Volkov, V.V., Kravchenko, T.A., and Roldughin V.I., Metal nanoparticles in catalytic polymer membranes and ion-exchange systems for advanced purification of water from molecular oxygen, Russ. Chem. Rev., 2013, vol. 82, no. 5, p. 465.
  5. Annenkov, V.V., Filina, E.A., Danilovtseva, E.N. et al., Complexes of poly(1-vinylimidazole) with aluminum ions in aqueous media, Polymer Science, Ser. A, 2002, vol. 44, no. 10, p. 1088.
  6. Izaak, T.I., Babkina, O.V., Lyamina, G.V., and Svetlichnyi, V.A., The formation of porous nickel-containing polyacrylate nanocomposites, Russian J. Phys. Chem. A, 2008, vol. 82, no. 12, p. 2111.
  7. Petrii, O.A., Electrosynthesis of nanostructures and nanomaterials., Russ. Chem. Rev., 2015, vol. 84, no. 2, p. 159.
  8. Hirai, Y. and Toshima, N., Polymeric Materials Encyclopedia, Ed. by J.C. Salamone, Tokyo: Boca Raton CRC Press, 1996, vol. 2, p. 1310.
  9. Mahouche-Cherguia, S., Guerrouachea, M., Garbenniera, B., and Chehimib, M.M., Coll. and Surf. A: Physicochem Eng. Aspect, 2013, vol. 439, p. 43.
  10. Margaryan, K.S., Sargsyan, S.H., and Sargsyan, A.S., Electrosynthesis of Metal-containing Polymeric Coatings Based on 1-Vinylimidazole and Acrylamide, Russ. J. Appl. Chem., 2016, vol. 89, no. 8, p. 1261.
  11. Margaryan, K.S., Sargsyan, S.H., and Sargsyan, A.S., Electrosynthesis of Nanocomposite Polymer Coatings Based on 1-Vinyl-1,2,4-triazole–Crotonaldehyde Copolymers, Russ. J. Appl. Chem., 2016, vol. 89, no. 9, p. 1556.
  12. Sargsyan, S.H., Margaryan, K.S., and Sargsyan, A.S., Metal-Containing Nanocomposites Based on 1-Vinyl-1,2,4-triazole–Crotonic Acid Copolymer, Russ. J. Appl. Chem., 2018, vol. 91, no. 2, p. 310.
  13. Khachatryan, S.F., Attaryan, O.S., Matsoyan, M.S., Kinoyan, F.S., and Asratyan, G.V., New method of N‑vinyimideazole synthesis, Khim. zhurn. Armenii, 2005, vol. 58, no. 1–2, p. 134.
  14. Vaculik, P., Chemie der Monomeren, Academy of Czechoslovakia, Prague, 1956.
  15. Prozorova, G.F., Korzhova, S.A., Kon’kova, T.V., et al., Synthesis and properties of silver and gold nanocomposites in poly(1-vinyl-1,2,4-triazole) matrix, Zh. strukt. khim., 2010. vol. 51, p. 109.
  16. Safronov, A.P., Tager, A.A., Sharina, S.V., Lopyrev, V.A., Ermakova, T.G., Tatarova, L.A., and Kashik, T.N., Nature of hydration in poly(1-vinylazole) aqueous solutions, Vysokomol. Soed. A. 1989, vol. 31, no. 12, p. 2662.
  17. Pozdnyakov, A.S., Emelyanov, A.I., Ermakova, T.G., and Prozorova, G.F., Functional polymer nanocomposites containing triazole and carboxyl groups, Polymer Sci., Ser. B, 2014, vol. 56, no. 2, p. 238.