Статья
2016
Abstract / Full Text

The process of electroxidative polymerization of magnesium 5,15-di(n-methoxyphenyl)porphine MgP(MeOPh)2 is studied. The presence of substituents in positions 5 and 15 of the porphine macroring makes reactive two of its four meso positions, which allows new bonds to be formed only in the opposite positions 10 and 20. As a result, the process of electropolymerization of this substituted monomer at its oxidation can produce only linear chains, in contrast to unsubstituted magnesium porphine MgP for which the polymer structure can both be linear and contain zigzag and/or cruciform fragments.

Author information
  • Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Oblast’, 142432, Russia

    D. V. Konev, O. I. Istakova & M. A. Vorotyntsev

  • Mendeleev University of Chemical Technology, Moscow, 125047, Russia

    D. V. Konev, O. I. Istakova & M. A. Vorotyntsev

  • Faculty of Chemistry, Moscow State University, Leninskie Gory, Moscow, 119991, Russia

    K. V. Lizgina & M. A. Vorotyntsev

  • Institute of Physiologically Active Compounds, Russian Academy of Sciences, Chernogolovka, Moscow Oblast’, 142432, Russia

    V. E. Baulin & I. P. Kalashnikova

  • Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    V. E. Baulin & I. P. Kalashnikova

  • Institute of Molecular Chemistry of the University of Burgundy, Dijon, France

    C. H. Devillers & M. A. Vorotyntsev

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