Статья
2020
Structure of Dimethylsulfoxide Water Solutions, According to Static Inductivity Data
E. S. Verstakov, S. A. Korobkova, T. A. Nosaeva
Российский журнал физической химии А
https://doi.org/10.1134/S003602442004024X
Abstract / Full Text
The static permittivity of water–DMSO mixtures is measured in the interval of 293–323 K throughout the range of concentrations of water–DMSO mixtures. Static permittivity values of the mixtures reveal a deviance from additivity that is maximal in the area of 0.3–0.4 molar shares of DMSO, where complexes 1DMSO–2H2O can form through H-bonds. The calculated values of the Kirkwood correlation factor gK indicate antiparallel orientation of DMSO dipoles, especially in the range of high DMSO concentrations of 0.7–1.0 molar shares.
Author information
- Volgograd State Medical University, 400131, Volgograd, RussiaE. S. Verstakov, S. A. Korobkova & T. A. Nosaeva
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