Статья
2022
Mechanism of the Reaction of Tris(trimethylsilyl)silane with Ozone
S. A. Grabovskiy
Российский журнал общей химии
https://doi.org/10.1134/S1070363222080114
Abstract / Full Text
Low-temperature (–90°C) ozonolysis of tris(trimethylsilyl)silane gave tris(trimethylsilyl)silanol and 1,1,1-trimethyl-2,2-bis(trimethylsiloxy)disilan-2-ol. The primary isotope effect in the reaction of tris(trimethylsilyl)silane with ozone at –90°C is equal to 5.5 and is consistent with the theoretical value calculated at the B3LYP/6-31+G(2d,p) level of theory assuming abstraction of H(D) from the Si–H(D) bond by ozone. Possible reaction mechanisms, namely radical, ionic, and ozone insertion into the Si–H bond, are discussed.
Author information
- Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences, 450054, Ufa, RussiaS. A. Grabovskiy
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