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Статья
2020

Synthesis and Electrochemical Properties of 2,5-Disubstituted Derivatives of 1,4-Bis(4,5-diphenylidimidazol-2-yl)benzene


A. V. DolganovA. V. Dolganov, O. Yu. GantsO. Yu. Gants, S. G. KostryukovS. G. Kostryukov, A. V. BalandinaA. V. Balandina, M. K. PryanichnikovaM. K. Pryanichnikova, A. Sh. KozlovA. Sh. Kozlov, Yu. I. LyukshinYu. I. Lyukshin, A. A. AkhmatovaA. A. Akhmatova, V. O. ZhirnovaV. O. Zhirnova, A. D. YudinaA. D. Yudina, A. S. TimoninaA. S. Timonina
Российский журнал общей химии
https://doi.org/10.1134/S1070363220060055
Abstract / Full Text

The data on the synthesis and electrochemical properties of 2,5-disubstituted derivatives of 1,4-bis(4,5-diphenyldimidazol-2-yl)benzene are reported. The effect of substituents on redox properties has been comprehensively investigated. The electrochemical reduction of quinones into the biradical occurs at positive potentials and is a result of two stages of single-electron transfer, through the stage of the monoradical formation. The correlation between the reduction potentials and the salts structure has been found.

Author information
  • N.P. Ogarev Mordovian National Research University, 430005, Saransk, RussiaA. V. Dolganov, O. Yu. Gants, S. G. Kostryukov, A. V. Balandina, M. K. Pryanichnikova, A. Sh. Kozlov, Yu. I. Lyukshin, A. A. Akhmatova, V. O. Zhirnova, A. D. Yudina & A. S. Timonina
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