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Статья
2017
Abstract / Full Text

Electrical transport in orthorhombic ytterbium and lutetium tungstates with Sc2(WO4)3 structural type was studied. It was proved by using two independent methods (EMF, dependence of conductivity on pressure of oxygen in the gas phase) that these phases are purely ionic conductors. It was found by Tubandt method for Lu2(WO4)3 the negligible contribution of the [WO4]2– anion into transport, which, together with the results of the EMF technique, indicates a predominantly oxygen character of conductivity.

Author information
  • Ural Federal University named after the first President of Russia B.N. Yeltsin, Yekaterinburg, 620002, Russia

    N. N. Pestereva, D. A. Lopatin, A. F. Guseva, E. L. Vostrotina, D. V. Korona & S. S. Nokhrin

References
  1. Imanaka, N., Kobayashi, Y., Fujiwara, K., Asano, T., Okazaki, Y., and Adachi, G., Chem. Mater., 1998, vol. 10, p. 2006.
  2. Kohler, J., Imanaka, N., and Adachi, G., J. Mater. Chem., 1999, vol. 9, p. 1357.
  3. Imanaka, N., Asano, T., Tamura, S., Kobayashi, Y., and Adachi, G., Electrochem. Solid-State Lett., 1999, vol. 2, p. 330.
  4. Imanaka, N., Hasegawa, Y., Yamaguchi, M., Itaya, M., Tamura, S., and Adachi, G., Chem. Mater., 2002, vol. 14, p. 4481.
  5. Imanaka, N., Masui, T., Kim., Y.W., and Adachi, G., J. Cryst. Growth, 2004, vol. 264, p. 134.
  6. Imanaka, N. and Tamura, S., Bull. Chem. Soc. Jpn., 2011, vol. 84, no. 4, p. 353.
  7. Adams, S., Bull. Mater. Sci., 2006, vol. 29, p. 587.
  8. Zhou, Y., Adams, S., Rao, P., Edwards, D.D., Neiman, A., and Pestereva, N., Chem. Mater., 2008, vol. 20, p. 6335.
  9. Zhou, Y., Rao, P., and Adams, S., Monatsh. Chem., 2009, vol. 140, p. 1017.
  10. Zhou, Y., Rao, P., and Adams, S., Solid State Ionics, 2011, vol. 192, no. 1, p. 34.
  11. Neiman, A.Ya., Pestereva, N.N., Zhou, Y., Nechaev, D.O., Koteneva, E.A., Vanec, K., Higgins, B., Volkova, N.A., and Korchuganova, I.G., Russ. J. Electrochem., 2013, vol. 49, p. 895.
  12. Zhou, Y., Neiman, A., and Adams, S., Phys. Status Solidi B, 2011, vol. 248, no. 1, p. 130.
  13. Pestereva, N.N., Safonova, I.G., Nokhrin, S.S., and Neiman, A.Ya., Russ. J. Inorg. Chem., 2010, vol. 55, p. 876.
  14. Rietveld, H.M., J. Appl. Crystallogr., 1969, vol. 2, p. 65.
  15. Grigor’eva, L.F., Diagrammy sostoyaniya sistem tugoplavkikh oksidov: Spravochnik. Vyp. 5. Dvoinye sistemy (State Diagrams of Systems of Refractory Oxides: Reference Book. Issue 5. Double Systems), Leningrad: Nauka, 1989, part 4, p. 284.
  16. Chebotin, V.N. and Perfil’ev, M.V., Elektrokhimiya tverdykh elektrolitov (Electrochemistry of Solid Solutions), Moscow Khimiya, 1978.