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Статья
2000

Electrochemical silylation of unsaturated organofluoric compounds


A. A. Stepanov A. A. Stepanov , B. I. Martynov B. I. Martynov , A. P. Tomilov A. P. Tomilov
Российский электрохимический журнал
https://doi.org/10.1007/BF02756905
Abstract / Full Text

Organofluoric compounds are electrolyzed in a diaphragmless cell filled with aprotic solvent containing trimethylchlorosilane. The following substances are trimethylsilylated in the electrolysis: C6F6, C6F5CI, C6F5H, C6F5CF3, C5F5N, CFC1=CFC1, and CF2=CFBr, with the introduction of one trimethylsilyl group. The silylation mechanism is established. In some case, the silylation products’ yield is increased on a copper cathode.

Author information
  • Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, GSP-1, 117813, Moscow, Russia

    A. A. Stepanov

  • Russian Research Institute of Organic Chemistry and Technology, sh. Entuziastov 23, 111024, Moscow, Russia

    B. I. Martynov & A. P. Tomilov

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