Статья
2019

Synthesis, Electrochemical and Antimicrobial Studies of Me6-Dibenzotetraazamacrocyclic Complexes of Ni(II) and Cu(II) Metal Ions


 Sweety Sweety , Vinod Kumar Vashistha Vinod Kumar Vashistha , Anuj Kumar Anuj Kumar , Randhir Singh Randhir Singh
Российский электрохимический журнал
https://doi.org/10.1134/S1023193519020113
Abstract / Full Text

Me6-dibenzotetraaza[14] annulene type macrocyclic complexes of Ni(II) and Cu(II) have been synthesized by template method and characterized by employing various techniques like molar conductance measurement, elemental (C, H, N) analysis, IR, UV-Vis, mass spectra and cyclic voltammetry. On the basis of electronic studies saddle shape distorted octahedral structure have been assigned to these macrocyclic complexes. The redox behavior of Ni(II) and Cu(II) macrocyclic complexes showed reversible and quasiirreversible redox process that supported by the ipc/ipa ratio which is in good agreement with Randles-Sevcik equation. These macrocyclic complexes were also studied for the antimicrobial activity against E. coli, P. aeruginosa, B. subtilis, S. aureus and C. albicans compared with Gentamycinas standard drug.

Author information
  • Department of Chemistry, Gurukula Kangri University, Haridwar, 249404, India

    Sweety, Anuj Kumar & Randhir Singh

  • Department of Chemistry, GLA University, Mathura, Uttar Pradesh, 281406, India

    Vinod Kumar Vashistha

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