Статья
2020

Diaphragmless Electrosynthesis of Diphenylphosphate


V. A. Zagumennov V. A. Zagumennov , I. P. Kosachev I. P. Kosachev
Российский электрохимический журнал
https://doi.org/10.1134/S1023193520090104
Abstract / Full Text

The process of mediated diaphragmless electrosynthesis (platinum anode, nickel cathode) of diphenylphosphate from diphenylphosphite with alkali metal halides (KI, LiBr) used as the mediator is studied in water‑organic (acetonitrile, benzene) medium. It is found that after passing 2 F per mole of diphenylphosphite through the electrolyte, two phosphorus-containing compounds are detected in the reaction mixture: original diphenylphosphite and target diphenylphosphate. The highest content of diphenylphosphate is observed when the electrosynthesis is carried out in the water‑acetonitrile‑benzene mixture. It is found that the excess of protons in the electrolyte accelerates the hydrolysis of original diphenylphosphite.

Author information
  • Kazan (Volga Region) Federal University, Butlerov Institute of Chemistry, 420018, Kazan, Russia

    V. A. Zagumennov

  • Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, 420088, Kazan, Russia

    I. P. Kosachev

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