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Статья
2021

Pd-Catalyzed asymmetric allylation involving bis(diamidophosphite) based on the salen-type chiral diamine


K. N. GavrilovK. N. Gavrilov, I. V. ChuchelkinI. V. Chuchelkin, V. K. GavrilovV. K. Gavrilov, S. V. ZheglovS. V. Zheglov, I. D. FirsinI. D. Firsin, V. M. TruninaV. M. Trunina, A. V. MaximychevA. V. Maximychev, A. M. PerepukhovA. M. Perepukhov
Российский химический вестник
https://doi.org/10.1007/s11172-021-3090-x
Abstract / Full Text

New bis(diamidophosphite) ligand with stereogenic phosphorus atoms in the 1,3,2-diaza-phospholidine rings was synthesized based on (1R,2R)-[N, N′-bis(3-hydroxybenzylidene)]-1,2-diaminocyclohexane. This ligand provided up to 73% ee in Pd-catalyzed asymmetric allylic alkylation of (E)-1,3-diphenylallyl acetate with dimethyl malonate and up to 80% ee in its amination with pyrrolidine, with the starting substrate conversion being quantitative.

Author information
  • S. A. Esenin Ryazan State University, 46 ul. Svobody, 390000, Ryazan, Russian FederationK. N. Gavrilov, I. V. Chuchelkin, V. K. Gavrilov, S. V. Zheglov, I. D. Firsin & V. M. Trunina
  • Moscow Institute of Physics and Technology (State University), 9 Institutskii per., 141701, Dolgoprudny, Moscow Region, Russian FederationA. V. Maximychev & A. M. Perepukhov
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