Статья
2020
Thermodynamic Properties of a Hyperbranched Pyridine-Containing Polyphenylene in the Range of T → 0 to 650 K
N. N. Smirnova, A. V. Markin, S. S. Sologubov, E. S. Serkova, N. V. Kuchkina, Z. B. Shifrina
Российский журнал физической химии А
https://doi.org/10.1134/S0036024420010318
Abstract / Full Text
The thermodynamic properties of amorphous hyperbranched pyridine-containing polyphenylene in the 6 to 650 K range of temperatures are studied for the first time via high-precision adiabatic vacuum calorimetry and differential scanning calorimetry. In the low-temperature range of 9 to 14 K, the polymer shows an anomalous change in heat capacity resembling the G transition in its shape. An exothermic effect is detected starting at T = 400 K, and is thought to be due to cross-linking in the studied sample. Standard thermodynamic functions of the polymer for the range of T → 0 to 400 K and the standard entropy of its formation at T = 298.15 K are calculated from the experimental data by means of classical thermodynamics.
Author information
- Lobachevsky State University of Nizhny Novgorod, 603950, Nizhny Novgorod, RussiaN. N. Smirnova, A. V. Markin & S. S. Sologubov
- Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, RussiaE. S. Serkova, N. V. Kuchkina & Z. B. Shifrina
References
- Hyperbranched Polymers: Synthesis, Properties, and Applications, Ed. by D. Yan, C. Gao, and H. Frey (Wiley, Hoboken, NJ, 2011).
- B. I. Voit and A. Lederer, Chem. Rev. 109, 5924 (2009).
- D. Konkolewicz, M. J. Monteiro, and S. Perrier, Macromolecules 44, 7067 (2011).
- G. R. Newkome and C. D. Shreiner, Polymer 49, 1 (2008).
- A. M. Muzafarov, N. G. Vasilenko, E. A. Tatarinova, G. M. Ignat’eva, V. M. Myakushev, M. A. Obrezkova, I. B. Meshkov, N. V. Voronina, and O. V. Novozhilov, Polymer Sci., Ser. C 53, 48 (2011).
- A. M. Muzafarov, E. A. Tatarinova, N. V. Vasilenko, et al., in Organosilicon Compounds: Experiment (Physico-Chemical Studies) and Applications, Ed. by V. Ya. Lee (Academic, Cambridge, MA, 2017), p. 323.
- X. Zheng, I. R. Oviedo, and L. J. Twyman, Macromolecules 41, 7776 (2008).
- N. Hu, J. Y. Yin, Q. Tang, et al., J. Polym. Sci., Part A 49, 3826 (2011).
- N. Baird, J. W. Dittmar, Y. B. Losovyj, et al., ACS Appl. Mater. Interfaces 9, 2285 (2017).
- W. Wu, R. Tang, Q. Li, et al., Chem. Soc. Rev. 44, 3997 (2015).
- H. Zhang, A. Patel, A. K. Gaharwar, et al., Biomacromolecules 14, 1299 (2013).
- R. Duncan and M. J. Vicent, Adv. Drug Deliv. Rev. 65, 60 (2013).
- S. Li, M. Omi, F. Cartieri, et al., Biomacromolecules 19, 3754 (2018).
- D. H. Wang, P. Mirau, B. Li, et al., Chem. Mater. 20, 1502 (2008).
- Y. Zheng, S. Li, Z. Weng, et al., Chem. Soc. Rev. 44, 4091 (2015).
- S. Ghiyasi, M. G. Sari, M. Shabanian, et al., Prog. Org. Coat. 120, 100 (2018).
- O. G. Zakharova, N. N. Smirnova, A. V. Markin, et al., Thermochim. Acta 468, 61 (2008).
- N. N. Smirnova, Yu. A. Zakharova, V. A. Ruchenin, and O. G. Zamyshlyayeva, Russ. J. Phys. Chem. A 86, 539 (2012).
- B. V. Lebedev, T. G. Kulagina, N. N. Smirnova, et al., J. Therm. Anal. Calorim. 74, 735 (2003).
- N. N. Smirnova, T. G. Kulagina, A. V. Markin, et al., Thermochim. Acta 425, 39 (2005).
- N. N. Smirnova, A. V. Markin, Yu. A. Zakharova, N. V. Kuchkina, A. L. Rusanov, and Z. B. Shifrina, Russ. Chem. Bull. 60, 132 (2011).
- N. N. Smirnova, Yu. A. Zakharova, A. V. Markin, N. V. Kuchkina, E. Yu. Yuzik-Klimova, and Z. B. Shifrina, Russ. Chem. Bull. 62, 2258 (2013).
- N. N. Smirnova, A. V. Markin, L. Ya. Tsvetkova, N. V. Kuchkina, E. Yu. Yuzik-Klimova and Z. B. Shifrina, Russ. J. Phys. Chem. A 90, 887 (2016).
- N. N. Smirnova, A. V. Markin, N. V. Kuchkina, E. Yu. Yuzik-Klimova, A. N. Shushunov and Z. B. Shifrina, Russ. J. Phys. Chem. A 90, 2321 (2016).
- N. N. Smirnova, Ya. S. Samosudova, A. V. Markin, et al., J. Chem. Thermodyn. 105, 443 (2017).
- N. V. Kuchkina, M. S. Zinatullina, E. S. Serkova, et al., RSC Adv. 5, 99510 (2015).
- N. V. Tsvetkov, A. S. Gubarev, E. V. Lebedeva, et al., Polym. Int. 66, 583 (2017).
- J. Meija, T. B. Coplen, M. Berglund, et al., Pure Appl. Chem. 88, 265 (2016).
- V. M. Malyshev, G. A. Mil’ner, E. L. Sorkin, et al., Prib. Tekh. Eksp., No. 6, 195 (1985).
- R. M. Varushchenko, A. I. Druzhinina, and E. L. Sorkin, J. Chem. Thermodyn. 29, 623 (1997).
- R. Sabbah, A. Xu-wu, J. S. Chickos, et al., Thermochim. Acta 331, 93 (1999).
- G. W. H. Höhne, W. F. Hemminger, and H.-J. Flammersheim, Differential Scanning Calorimetry (Springer, Berlin, Heidelberg, 2003).
- V. A. Drebushchak, J. Therm. Anal. Calorim. 79, 213 (2005).
- B. Wunderlich and H. Bauer, Heat Capacities of Linear Polymers (Springer, Berlin, 1970).
- G. Adam and J. H. Gibbs, J. Chem. Phys. 43, 139 (1965).
- W. Kauzmann, Chem. Rev. 43, 219 (1948).
- A. B. Bestul and S. S. Chang, J. Chem. Phys. 40, 3731 (1964).
- V. B. Lazarev, A. D. Izotov, K. S. Gavrichev, et al., Thermochim. Acta 269–270, 109 (1995).
- O. V. Shebershneva, A. D. Izotov, K. S. Gavrichev, and V. B. Lazarev, Inorg. Mater. 32, 28 (1996).
- P. Debye, Ann. Phys. (N.Y.) 344, 789 (1912).
- Experimental Thermodynamics, Vol. 1: Calorimetry of Non-Reacting Systems, Ed. by J. P. McCullough and D. W. Scott (Butterworth, London, 1968).
- M. W. Chase, Jr., J. Phys. Chem. Ref. Data, Monograph 1–2 (9), 1 (1998).