Статья
2021
Thermal Properties of Cobalt(II) β-Iminoketonates
S. I. Dorovskikh, P. А. Stabnikov, L. N. Zelenina, S. V. Sysoev, N. B. Morozova
Российский журнал общей химии
https://doi.org/10.1134/S107036322110008X
Abstract / Full Text
Thermogravimetry, differential scanning calorimetry, and flow methods were used to investigate thermal properties of a series of cobalt(II) β-iminoketonates [R2C(NR1)CHC(O)R2]. The consecutive order of their volatility was determined. The complexes do not decompose up to melting and do not undergo phase transitions. For the complex (R1 = Н, R2 = Me) the temperature dependence of sublimation ln (p/p0) = 32.02 ‒ 16822/T(K) at 402.6‒433.7 K was measured and the values of ΔsublH°Т* = 140±4 kJ/mol and ΔsublS°Т* = 266±10 J/(K·mol) were calculated.
Author information
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, RussiaS. I. Dorovskikh, P. А. Stabnikov, L. N. Zelenina, S. V. Sysoev & N. B. Morozova
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