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Статья
2021

2,4-Dichloro-5-(2,4,6-trimethoxyphenyl)cyclopent-4-ene-1,3-dione derivatives in the reaction with CrCl2


V. A. EgorovV. A. Egorov, L. M. KhalilovL. M. Khalilov, E. S. MescheryakovaE. S. Mescheryakova, F. A. GimalovaF. A. Gimalova, M. S. MiftakhovM. S. Miftakhov
Российский химический вестник
https://doi.org/10.1007/s11172-021-3066-x
Abstract / Full Text

The reactions of 2,4-dichloro-5-(2,4,6-trimethoxyphenyl)cyclopent-4-ene-1,3-dione and its 2-allyl derivative with CrCl2 were studied. Both reactions are accompanied by the saturation of the cyclopentenone double bond and the simultaneous reductive dechlorination of chlorine-containing centers. The structure of the final allyl-containing product was determined by X-ray diffraction.

Author information
  • Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences, 69 prosp. Oktyabrya, 450054, Ufa, Russian FederationV. A. Egorov, F. A. Gimalova & M. S. Miftakhov
  • Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian FederationL. M. Khalilov & E. S. Mescheryakova
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