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Статья
2020

Reactions of CH acids with the Michael acceptors in the presence of potassium carbonate


D. S. KhachatryanD. S. Khachatryan, I. I. BoikoI. I. Boiko, A. V. KolotaevA. V. Kolotaev, K. R. MatevosyanK. R. Matevosyan
Российский химический вестник
https://doi.org/10.1007/s11172-020-2764-0
Abstract / Full Text

New 2-cyclohexenone derivatives were synthesized via the Michael reaction in the presence of potassium carbonate. These derivatives containing the acetyl substituent in position 6 are of special interest due to the ability to form boron chelate complexes, 1,3-dioxaborines, possessing luminescence properties. The dependence of the position of the absorption and luminescence absorption band maxima on the donor properties of the substituents was found.

Author information
  • Institute of Chemical Reagents and High Purity Chemical Substances of the National Research Centre Kurchatov Institute, 3 Bogorodsky val, 107076, Moscow, Russian FederationD. S. Khachatryan & A. V. Kolotaev
  • Technolog Co. Ltd., Build. 157, 2 Mendeleevskaya ul., 152025 Pereslavl-Zalessky, Yaroslavl Region, Russian FederationI. I. Boiko
  • D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya pl., 125047, Moscow, Russian FederationK. R. Matevosyan
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