Статья
2021
Reactive Adsorption Desulfurization of Dibenzothiophene in Presence of Mesoporous Adsorbents
O. V. Golubev, H. Zhou, E. A. Karakhanov
Российский журнал прикладной химии
https://doi.org/10.1134/S1070427221050050
Abstract / Full Text
Reactive adsorption desulfurization of a model fuel containing dibenzothiophene with various adsorbents was studied. Adsorbents based on MCM-41 mesoporous material with supported Ni and ZnO phases were prepared and characterized. The desulfurization activity of the material in a fixed-bed flow-through reactor was compared to that of alumina-based adsorbents. The adsorbent based on MCM-41 considerably surpasses its analog on Al2O3 support in the adsorption capacity in reactive adsorption desulfurization of dibenzothiophene at 350°С, pressure of 2 MPa, and feed space velocity of 1 h–1.
Author information
- Chemical Faculty, Moscow State University, 119991, Moscow, RussiaO. V. Golubev, H. Zhou & E. A. Karakhanov
References
- Kampouraki, Z.C., Giannakoudakis, D.A., Triantafyllidis, K.S., and Deliyanni, E.A., Green Chem., 2019, vol. 21, pp. 6685–6698. https://doi.org/10.1039/C9GC03234G
- Eseva, E.A., Akopyan, A.V., Anisimov, A.V., and Maximov, A.L., Petrol. Chem., 2020, vol. 60, no. 9, pp. 979–990. https://doi.org/10.1134/S0965544120090091
- Shiraishi, Y., Tachibana, K., Hirai, T., and Komasawa, I., Ind. Eng. Chem. Res., 2002, vol. 41, pp. 4362–4375. https://doi.org/10.1021/ie010618x
- Choi, E.S., Roces, S., Dugos, N., Arcega, A., and Wan, M.-W., J. Clean. Prod., 2017, vol. 161, pp. 267–276. https://doi.org/10.1016/j.jclepro.2017.05.072
- Maity, U., Basu, J.K., and Sengupta, S., Fuel Process. Technol., 2014, vol. 121, pp. 119–124. https://doi.org/10.1016/j.fuproc.2014.01.012
- Patent US 6254766 B1, Publ. 2001.
- Zhang, Y., Yang, Y., Lin, F., Yang, M., Liu, T., Jiang, Z., and Li, C., Chin. J. Catal., 2013, vol. 34, pp. 140–145. https://doi.org/10.1016/S1872-2067(11)60513-5
- Liu, Y., Pan, Y., Wang, H., Liu, Y., and Liu, C., Chin. J. Catal., 2018, vol. 39, pp. 1543–1551. https://doi.org/10.1016/S1872-2067(18)63085-2
- Ullah, R., Bai, P., Wu, P., Liu, B., Subhan, F., and Yan, Z., Micropor. Mesopor. Mater., 2017, vol. 238, pp. 36–45. https://doi.org/10.1016/j.micromeso.2016.02.037
- Naranov, E.R., Dement’ev, K.I., Gerzeliev, I.M., Kolesnichenko, N.V., Roldugina, E.A., and Maksimov, A.L., Petrol. Chem., 2019, vol. 59, pp. 247–261. https://doi.org/10.1134/S0965544121030105
- Naranov, E., Golubev, O., Zanaveskin, K., Guseva, A., Nikulshin, P., Kolyagin, Y., Maximov, A., and Karakhanov, E., ACS Omega, 2020, vol. 5, no. 12, pp. 6611–6618. https://doi.org/10.1021/acsomega.9b04373
- Sing, K.S.W., Everett, D.H., Haul, R.A.W., Moscou, L., Pierotti, R.A., Rouquerol, J., and Siemieniewska, T., Pure Appl. Chem., 1985, vol. 57, pp. 603–619. https://doi.org/10.1351/pac198557040603
- Silvestre-Albero, J., Sepúlveda-Escribano, A., and Rodríguez Reinoso, F., Micropor. Mesopor. Mater., 2008, vol. 113, pp. 362–369. https://doi.org/10.1016/j.micromeso.2007.11.037
- Kresge, C.T., Leonowicz, M.E., Roth, W.J., Vartuli, J.C., and Beck, J.S., Nature, 1992, vol. 359, pp. 710–712. https://doi.org/10.1038/359710a0
- Lyu, Y., Sun, Z., Xin, Y., Liu, Y., Wang, C., and Liu, X., Chem. Eng. J., 2019, vol. 374, pp. 1109–1117. https://doi.org/10.1016/j.cej.2019.06.01