Статья
2022

Solid-State Synthesis of SnO2–Zn2SnO4 Nanocomposite and Its Application for Electrochemical Detection of Cabergoline as Dopamine Receptor Antagonists


 Masoumeh Taei Masoumeh Taei ,  Masoud Fouladgar Masoud Fouladgar
Российский электрохимический журнал
https://doi.org/10.1134/S1023193522010141
Abstract / Full Text

In the present work, the synthesis of SnO2–Zn2SnO4 nanocomposite was fulfilled according to solid-state technique followed by calcination. The SnO2–Zn2SnO4 nanocomposites were specified by X-ray diffraction and scanning electron microscopy. Then, oxidation response of cabergoline (Cab) was investigated on the surface of SnO2–Zn2SnO4 modified carbon paste electrode (SnO2–Zn2SnO4/CPE), exhibiting a well-defined single oxidation peak at +0.84 V vs. Ag/AgCl, NaCl (3 M) in an irreversible process. In oxidation reaction of Cab, equal number of protons and electrons are participated and the oxidation reaction rate is controlled by an adsorption step. The calibration curve from differential pulse voltammetry showed linearity in the concentration range of 3.0 to 155.0 µM (R2 = 0.9936) and detection limit was calculated to be 0.01 µM. The analysis results certified that SnO2–Zn2SnO4/CPE possess considerable potential to detect Cab in biological fluids.

Author information
  • Department of Chemistry, Payame Noor University, 19395-4697, Tehran, Iran

    Masoumeh Taei

  • Department of Biochemistry, Falavarjan Branch, Islamic Azad University, Isfahan, Iran

    Masoud Fouladgar

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