Modifying Copper and Copper Alloy Surface with Depocolin and 5-Chloro-1,2,3-Benzotriazole from a Neutral Aqueous Solution
M. O. Agafonkina, O. Yu. Grafov, N. P. Andreeva, L. P. Kazanskii, Yu. I. Kuznetsov
Российский журнал физической химии А
https://doi.org/10.1134/S0036024421110029
Results are presented from adsorption and electrochemical investigations of a 3,7,12,17-tetramethyl-8,13-divinyl-2,18-deuteroporphyrin IX (depocolin) salt on a CuNiFe (MNZh) 5-1 alloy. It is established that modifying surfaces of copper and CuNiFe 5-1 alloy with depocolin and the subsequent adsorption of 5-chloro-1,2,3-benzotriazole considerably enhances the protective effect, which is higher than those of each compound taken separately. XPS and reflection ellipsometry reveal the chemisorptive character of interaction between depocolin and the alloy’s surface. It is shown that bonding between the inhibitor and the copper or alloy surface proceeds through carboxyl groups of depocolin, while the porphyrin cycle does not participate in this interaction.
- Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, RussiaM. O. Agafonkina, O. Yu. Grafov, N. P. Andreeva, L. P. Kazanskii & Yu. I. Kuznetsov
- Yu. I. Kuznetsov and L. P. Kazansky, Russ. Chem. Rev. 77, 219 (2008).https://doi.org/10.1070/RC2008v077n03ABEH003753
- M. Finšgar and I. Milošev, Corros. Sci. 52, 2737 (2010). https://doi.org/10.1016/j.corsci.2010.05.002
- M. Antonijević Milan, M. Milić Snežana, and B. Petrović Marija, Corros. Sci. 51, 1228 (2009). https://doi.org/10.1016/j.corsci.2009.03.026
- Y. Rio, M. S. Rodríguez-Morgade, and T. Torres, Org. Biomol. Chem. 6, 1877 (2008). https://doi.org/10.1002/chin.200836268
- M. V. Martínez-Díaz, G. de la Torre, and T. Torres, Chem. Commun. 46, 7090 (2010). https://doi.org/10.1039/c0cc02213f
- G. Bottari, O. Trukhina, M. Ince, and T. Torres, Coord. Chem. Rev. 256, 2453 (2012). https://doi.org/10.1016/j.ccr.2012.03.011
- N. P. Andreeva, A. V. Larionov, O. Yu. Grafov, et al., Korroz.: Mater., Zashch., No. 10, 22 (2016). N. P. Andreeva, A. V. Larionov, O. Yu. Grafov, et al., Prot. Met. Phys. Chem. Surf. 54, 1276 (2018). https://doi.org/10.1134/S2070205118070031
- I. V. Aoki, I. C. Guedes, and S. L. A. Maranhao, J. Appl. Electrochem. 32, 915 (2002). https://doi.org/10.1023/A:1020506432003
- S. Lokesh Koodlur, M. de Keersmaecker, A. Elia, et al., Corros. Sci. 62, 73 (2012). https://doi.org/10.1016/j.corsci.2012.04.037
- J. C. Valle-Quitana, G. F. Dominguez-Patiño, and J. G. Gonzalez-Rodriguez, Corrosion 2014, 945645 (2014).
- Y. Feng, S. Chen, W. Guo, et al., J. Electroanal. Chem. 602, 115 (2007). https://doi.org/10.1016/j.jelechem.2006.12.016
- A. Singh, Y. Lin, M. A. Quraishi, et al., Molecules 20, 15122 (2015). https://doi.org/10.3390/modules200815122
- J. Hu, D. Huang, G. Zhang, et al., Corros. Sci. 63, 367 (2012). https://doi.org/10.1149/2.021206esl
- Yu. I. Kuznetsov, M. O. Agafonkina, N. P. Andreeva, and L. P. Kazansky, Corros. Sci. 100, 535 (2015). https://doi.org/10.1016/j.corsci.2015.08.028
- O. Yu. Grafov, L. P. Kazansky, S. V. Dubinskaya, and Yu. I. Kuznetsov, Int. J. Corros. Scale Inhib. 8, 549 (2019). https://doi.org/10.17675/2305-6894-2019-8-3-6
- R. Azzam and N. Bashara, Ellipsometry and Polarized Light (North-Holland, Amsterdam, 1977).
- M. O. Agafonkina, N. P. Andreeva, Yu. I. Kuznetsov, and S. F. Timashev, Russ. J. Phys. Chem. A 91, 1414 (2017). https://doi.org/10.7868/S0044453717080027
- D. A. Shirley, Phys. Rev. B 5, 4709 (1972). https://doi.org/10.1103/Phys.Rev.B.72.245319
- H. Scofield, J. Electron Spectrosc. Relat. Phenom. 8, 129 (1976).
- M. Mohai, Surf. Interface Anal. 36, 828 (2004). https://doi.org/10.1002/sia.1775
- P. J. Cumpson and M. P. Seah, Surf. Interface Anal. 25, 430 (1997). https://doi.org/10.1002/(SICI)1096-9918(199706)25:6<430::AID-SIA254>3.0.CO;2-7
- C. Battistoni, G. Mattogno, E. Paparazzo, and L. Naldini, Inorg. Chim. Acta 102, 1 (1985). https://doi.org/10.1016/S0020-1693(00)89066-0
- C. E. Dube, B. Workie, S. P. Kounaves, A. Robbat, et al., J. Electrochem. Soc. 142, 3357 (1995).
- N. S. McIntyre and M. G. Cook, Anal. Chem. 47, 2208 (1975). https://doi.org/10.1021/ac60363a034
- N. S. McIntyre and D. G. Zetaruk, Anal. Chem. 49, 1521 (1977). https://doi.org/10.1021/ac50019a016
- D. D. Hawn and B. M. de Koven, Surf. Interface Anal. 10, 63 (1987). https://doi.org/10.1002/sia.740100203
- K. Lian, D. W. Kirk, and S. J. Thorpe, Electrochim. Acta 37, 2029 (1992). https://doi.org/10.1016/0013-4686(92)87119-K
- E. Khawaja, M. Salim, M. Khan, et al., J. Non-Cryst. Solids 110, 33 (1989). https://doi.org/10.1016/0022-3093(89)90179-8
- C. L. Bianchi, M. G. Cattania, and P. Villa, Appl. Surf. Sci. 70, 211 (1993). https://doi.org/10.1016/0169-4332(93)90429-F
- T. Dickinson, A. F. Povey, and P. M. A. Sherwood, J. Chem. Soc. Faraday Trans. 1, No. 73, 327 (1977). https://doi.org/10.1039/F19777300327