TiO2/Fe3O4/Multiwalled Carbon Nanotubes Nanocomposite as Sensing Platform for Simultaneous Determination of Morphine and Diclofenac at a Carbon Paste Electrode

Ebrahim Dasht Razmi Ebrahim Dasht Razmi , Hadi Beitollahi Hadi Beitollahi , Masoud Torkzadeh Mahani Masoud Torkzadeh Mahani , Marzieh Anjomshoa Marzieh Anjomshoa
Российский электрохимический журнал
Abstract / Full Text

A nanocomposite of TiO2/Fe3O4/MWCNTs (TFMWCNT) and ionic liquid was used to fabrication of a novel modified carbon paste electrode. The modified electrode was used for voltammetric determination of morphine. The proposed method exhibited wide linear dynamic range of 2.5 × 10–8 to 6.0 × 10–4 M with a detection limit (S/N = 3) of 1.5 × 10–8 M for morphine. Also, the diffusion coefficient (D = 2.83 × 10–6 cm2/s) and electron transfer coefficient (α = 0.31) for morphine oxidation were also determined. The novel sensor was used for simultaneous determination of morphine and diclofenac using square wave voltammetry (SWV). Finally this method was used for determination of morphine and diclofenac in some real samples.

Author information
  • Department of Chemistry, Graduate University of Advanced Technology, Kerman, Iran

    Ebrahim Dasht Razmi

  • Environment Department, Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, Kerman, Iran

    Hadi Beitollahi

  • Department of Biotechnology, Institute of Science, High Technology and Environmental Science, Graduate University of Advanced Technology, Kerman, Iran

    Masoud Torkzadeh Mahani & Marzieh Anjomshoa

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