Статья
2017

On the impedance response of reactions influenced by mass transfer


Mai T. T. Tran Mai T. T. Tran , Bernard Tribollet Bernard Tribollet , Vincent Vivier Vincent Vivier , Mark E. Orazem Mark E. Orazem
Российский электрохимический журнал
https://doi.org/10.1134/S1023193517090142
Abstract / Full Text

A direct relationship is derived between the charge-transfer resistance and the resistive terms ascribable to diffusion for a faradaic reaction influenced by transport of the reacting species to the electrode. The charge-transfer resistance is shown to approach a finite value for potentials at which the current is limited by mass transfer and, conversely, the diffusion impedance approaches a finite value when the current is controlled by kinetics. Supporting experimental results are presented for both an irreversible (oxygen reduction reaction) and a quasi-reversible (ferrocyanide oxidation) electrochemical systems investigated with a rotating- disk electrode.

Author information
  • Laboratoire Interfaces et Systèmes Electrochimiques, Sorbonne Universités, UPMC Univ Paris 06, CNRS, Paris, F-75005, France

    Mai T. T. Tran, Bernard Tribollet & Vincent Vivier

  • Department of Chemical Engineering, University of Florida, Gainesville, FL, 32611, USA

    Mark E. Orazem

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