Phase Transitions in the Bulk and on Surfaces of Titanium Dioxide during Heat Treatment
E. A. Sosnov, A. Yu. Shevkina, A. A. Malkov, A. A. Malygin
Российский журнал физической химии А
https://doi.org/10.1134/S003602442201023X
Powder X-ray diffraction (XRD), atomic force microscopy (AFM), and electronic spectroscopy of diffuse reflectance (ESDR) are used to study phase transformations that occur during the heat treatment of P25 Degussa and AK-1 titanium dioxides synthesized via the hydrolysis of titanium tetrachloride (anatase modification). It is shown that separating the ESDR spectra into the components described by the Fermi–Dirac distribution reveals the coordination state of atoms on the surfaces of materials. A relationship is found that allows estimates of the area occupied by anatase- and rutile-like coordination polyhedra in two-phase titanium oxide systems, based on spectroscopic data (ESDR). It is found that a change in the phase composition of titanium dioxide detected by XRD is preceded by another in the coordination state of the surface polyhedral, according to spectra of diffuse reflectance. A change in the coordination of titanium oxide structures occurs at 100–200°C lower than the detection of the phase transition. Mechanisms for anatase/rutile phase transitions in one- and two-phase titanium oxide systems are proposed.
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