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Статья
2020

Hydroxy-containing ionic liquids as catalysts in the synthesis of organic carbonates from epoxides and CO2


S. E. LyubimovS. E. Lyubimov, A. A. ZvinchukA. A. Zvinchuk, B. ChowdhuryB. Chowdhury, V. A. DavankovV. A. Davankov
Российский химический вестник
https://doi.org/10.1007/s11172-020-2941-1
Abstract / Full Text

Hydroxy-containing ionic liquids such as triethyl(3-hydroxypropyl)ammonium, 1-(3-hydroxypropyl)-3-methylimidazolium, 3-(2-hydroxyethyl)-1-methylimidazolium, and 1-(3-hydroxypropyl)pyridinium chlorides were used as catalysts for the addition of carbon dioxide to epoxides, which gives cyclic carbonates. The effect of CO2 pressure and reaction temperature on the conversion of epoxides, as well as a promoting effect of inorganic substrates were studied.

Author information
  • A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian FederationS. E. Lyubimov, A. A. Zvinchuk & V. A. Davankov
  • Indian Institute of Technology (Indian School of Mines), 826004, Dhanbad, IndiaB. Chowdhury
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