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Статья
2020

Tetrakis(4-bromophenoxy)phthalocyanine, its metal complexes, and their sulfonated derivatives: the synthesis and spectral properties


A. S. VashurinA. S. Vashurin, T. V. TikhomirovaT. V. Tikhomirova, A. A. FilippovaA. A. Filippova, N. A. FutermanN. A. Futerman, V. E. MaizlishV. E. Maizlish, Yu. S. MarfinYu. S. Marfin
Российский химический вестник
https://doi.org/10.1007/s11172-020-2909-1
Abstract / Full Text

Tetrakis(4-bromophenoxy)phthalocyanine and its metal complexes (M = Mg, Co, Cu, Zn) were synthesized. Sulfochlorination of these compounds followed by hydrolysis of the sulfochlorides gave tetrakis(2-sulfo-4-bromophenoxy)phthalocyanine and corresponding sulfonated metallophthalocyanines (except M = Cu). Spectral properties of the compounds synthesized were investigated. It was shown that the introduction of sulfo groups leads to a bathochromic shift of the Q-band in the absorption spectra recorded in DMF and to a hypsochromic shift of the Q-band in the absorption spectra recorded in sulfuric acid.

Author information
  • Ivanovo State University of Chemistry and Technology, 7 Sheremetevsky prosp., 153000, Ivanovo, Russian FederationA. S. Vashurin, T. V. Tikhomirova, A. A. Filippova, N. A. Futerman, V. E. Maizlish & Yu. S. Marfin
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