Статья
2020
Tetrakis(4-bromophenoxy)phthalocyanine, its metal complexes, and their sulfonated derivatives: the synthesis and spectral properties
A. S. Vashurin, T. V. Tikhomirova, A. A. Filippova, N. A. Futerman, V. E. Maizlish, Yu. S. Marfin
Российский химический вестник
https://doi.org/10.1007/s11172-020-2909-1
Abstract / Full Text
Tetrakis(4-bromophenoxy)phthalocyanine and its metal complexes (M = Mg, Co, Cu, Zn) were synthesized. Sulfochlorination of these compounds followed by hydrolysis of the sulfochlorides gave tetrakis(2-sulfo-4-bromophenoxy)phthalocyanine and corresponding sulfonated metallophthalocyanines (except M = Cu). Spectral properties of the compounds synthesized were investigated. It was shown that the introduction of sulfo groups leads to a bathochromic shift of the Q-band in the absorption spectra recorded in DMF and to a hypsochromic shift of the Q-band in the absorption spectra recorded in sulfuric acid.
Author information
- Ivanovo State University of Chemistry and Technology, 7 Sheremetevsky prosp., 153000, Ivanovo, Russian FederationA. S. Vashurin, T. V. Tikhomirova, A. A. Filippova, N. A. Futerman, V. E. Maizlish & Yu. S. Marfin
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