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Статья
2021

Si3S-Bicyclo[1.1.0]butane vs. Si3S-cyclobutene: an isomeric interplay*


V. Ya. LeeV. Ya. Lee, S. MiyazakiS. Miyazaki, O. A. GapurenkoO. A. Gapurenko, R. M. MinyaevR. M. Minyaev, V. I. MinkinV. I. Minkin, A. SekiguchiA. Sekiguchi
Российский химический вестник
https://doi.org/10.1007/s11172-021-3338-5
Abstract / Full Text

(Thiatrisila)bicyclo[1.1.0]butane 1 quantitatively transformed under either photochemical or thermal conditions into the isomeric (thiatrisila)cyclobutene 2, which was isolated and fully characterized.

Author information
  • Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, 305-8571, Tsukuba, Ibaraki, JapanV. Ya. Lee, S. Miyazaki & A. Sekiguchi
  • Institute of Physical and Organic Chemistry, Southern Federal University, 194/2 prosp. Stachki, 344090, Rostov-on-Don, Russian FederationO. A. Gapurenko, R. M. Minyaev & V. I. Minkin
References
  1. R. B. Woodward, R. Hoffmann, The Conservation of Orbital Symmetry, Academic Press, 1971.
  2. V. Ya. Lee, H. Yasuda, A. Sekiguchi, J. Am. Chem. Soc., 2007, 129, 2436.
  3. V. Ya. Lee, S. Miyazaki, H. Yasuda, A. Sekiguchi, J. Am. Chem. Soc., 2008, 130, 2758.
  4. V. Ya. Lee, O. A. Gapurenko, S. Miyazaki, A. Sekiguchi, R. M. Minyaev, V. I. Minkin, H. Gornitzka, Angew. Chem., Int. Ed., 2015, 54, 14118.
  5. Gaussian 16, Revision C.01, Gaussian, Inc., Wallingford (CT), 2019.
  6. V. Ya. Lee, A. Sekiguchi, Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds, Wiley, Chichester, 2010, Ch. 5, pp. 199–334.