Article
2022

Codeposition of Zinc with Manganese from Different Gluconate Baths

Karolina Chat-Wilk Karolina Chat-Wilk , Ewa Rudnik Ewa Rudnik , Grzegorz Włoch Grzegorz Włoch , Piotr Osuch Piotr Osuch
Russian Journal of Electrochemistry
https://doi.org/10.1134/S1023193522030053
Abstract / Full Text
Karolina Chat-Wilk, Rudnik, E., Włoch, G. et al. Codeposition of Zinc with Manganese from Different Gluconate Baths. Russ J Electrochem 58, 168–183 (2022). https://doi.org/10.1134/S1023193522030053

Codeposition of zinc and manganese from slightly acidic gluconate solutions with various anions (chloride and/or sulfate) showed that independently on the bath speciation manganese ions were a key factor inhibiting electroreduction of zinc ions. It resulted in two potential ranges of the electrodeposition behavior. Morphology and composition of the electrodeposits was not affected by the type of anions in the electrolyte, but was seriously dependent on a deposition potential. Nucleation mode, surface wettability and corrosion properties of the deposits were also discussed.

Author information

  • AGH University of Science and Technology, Faculty of Non-Ferrous Metals, 30-059, Cracow, Poland

    Karolina Chat-Wilk, Ewa Rudnik, Grzegorz Włoch & Piotr Osuch

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