Article
2018
Synthesis and Spectral Characteristics of Sn(IV) Tetraphenylporphyrinates
N. V. Chizhova, A. V. Shinkarenko, N. Zh. Mamardashvili
Russian Journal of General Chemistry
https://doi.org/10.1134/S1070363218120162
Abstract / Full Text
Coordination reactions of 5,10,15,20-tetraphenylporphyrin, 2-bromo-5,10,15,20-tetraphenylporphyrin, 2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrin, 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrin and metal-exchange reactions of their cadmium complexes with tin(II) chloride in dimethylformamide are described. Optimum conditions for the synthesis of Sn(IV) tetraphenylporphyrinates have been elaborated. The obtained substances have been identified by electron absorption spectroscopy, 1H NMR spectroscopy, and mass-spectroscopy.
Author information
- Krestov Institute of Solutions Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, RussiaN. V. Chizhova & N. Zh. Mamardashvili
- Ivanovo State University of Chemistry and Technology, Ivanovo, RussiaA. V. Shinkarenko
References
- Porfiriny: spektroskopiya, elektrokhimiya, primenenie (Porphyrins: Spectroscopy, Electrochemistry, Application), Enikolopyan, N.S., Ed., Moscow: Nauka, 1987.
- Arnold, D.P. and Blok, J., Coord. Chem. Rev. 2004, vol. 48, p. 299. doi https://doi.org/10.1016/j.ccr.2004.01.004
- Slodek, A., Schnurpfeil, G., and Wohrli, D., J. Porph. Phthalocyan., 2011, vol. 21, p. 811. doi https://doi.org/10.1142/S1088424617500833
- Berezin, B.D., Koordinatsionnye soedineniya porfirinov i ftalotsianina (Coordination Compounds of Porphyrins and Phthalocyanine), Moscow: Nauka, 1978.
- Zvezdina, S.V., Mal’tseva, O.V., Chizhova, N.V., and Mamardashvili, N.Zh., Macroheterocycles 2014, vol. 7, no. 3, p. 276. doi https://doi.org/10.6060/mhc140492m
- Mal’tseva, O.V., Chizhova, N.V., Kumeev, R.S., and Mamardashvili, N.Zh., Macroheterocycl. 2017, vol. 10, no. 1, p. 68. doi https://doi.org/10.6060/mhc160541c
- Chizhova, N.V., Mal’tseva, O.V., Zav’yalov, A.V., and Mamardashvili, N.Zh., Russ. J. Inorg. Chem. 2017, vol. 62, no. 5, p. 683. doi https://doi.org/10.1134/S0036023617050072
- Zvezdina, S.V., Chizhova, N.V., and Mamardashvili, N.Zh., Russ. J. Inorg. Chem. 2017, vol. 62, no. 4, p. 517. doi https://doi.org/10.1134/S0036023617040222
- Hembrait, P., Usp. Khim. 1977, vol. 46, no. 7, p. 1207.
- Lembo, A., Tagliatesta, P., and Guldi, D.M., J. Phys. Chem. (A), 2006, vol. 110, no. 40, p. 11424. doi https://doi.org/10.1021/jp062735h
- Atkinson, S.T., Brady, S.P., James, J.P., and Nolan, K.B., Pure Appl. Chem. 1995, vol. 67, no. 7, p. 1109. doi https://doi.org/10.1351/pac199567071109
- Kumar, P.K., Bhyrappa, P., and Varghese, B., Tetrahedron Lett. 2003, vol. 44, p. 4849. doi https://doi.org/10.1016/S004039(03)01143-2
- Chizhova, N.V., Ivanova, Yu.B., and Mamardashvili, N.Zh., Macroheterotsycly 2018, vol. 11, no. 1, p. 85. doi https://doi.org/10.6060/mhc171265c
- Maltseva, O.V., Zvezdina S.V.,Chizhova, N.V., and Mamardashvili, N.Zh., Russ. J. Gen. Chem. 2016, vol. 86, no. 1, p. 102. doi https://doi.org/10.1134/S1070363216010187
- Bhyrappa, Р. and Krishnan, V., Inorg. Chem. 1991, vol. 30, p. 239. doi 1021/ic00002a018