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Article
2018

Synthesis and Spectral Characteristics of Sn(IV) Tetraphenylporphyrinates


N. V. ChizhovaN. V. Chizhova, A. V. ShinkarenkoA. V. Shinkarenko, N. Zh. MamardashviliN. Zh. Mamardashvili
Russian Journal of General Chemistry
https://doi.org/10.1134/S1070363218120162
Abstract / Full Text

Coordination reactions of 5,10,15,20-tetraphenylporphyrin, 2-bromo-5,10,15,20-tetraphenylporphyrin, 2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrin, 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrin and metal-exchange reactions of their cadmium complexes with tin(II) chloride in dimethylformamide are described. Optimum conditions for the synthesis of Sn(IV) tetraphenylporphyrinates have been elaborated. The obtained substances have been identified by electron absorption spectroscopy, 1H NMR spectroscopy, and mass-spectroscopy.

Author information
  • Krestov Institute of Solutions Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, RussiaN. V. Chizhova & N. Zh. Mamardashvili
  • Ivanovo State University of Chemistry and Technology, Ivanovo, RussiaA. V. Shinkarenko
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