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Article
2018

Chemisorption Activity of Mercury(II) Cyclopentamethylenedithiocarbamate: Synthesis, Structure, and Thermal Behavior of the [Hg2{S2CN(CH2)5}4] and [Au3{S2CN(CH2)5}6][Au{S2CN(CH2)5}2][Hg2Cl6]2 Complexes


O. V. LosevaO. V. Loseva, T. A. RodinaT. A. Rodina, O. N. AntzutkinO. N. Antzutkin, A. V. IvanovA. V. Ivanov
Russian Journal of General Chemistry
https://doi.org/10.1134/S1070363218120149
Abstract / Full Text

The dinuclear complex mercury(II) cyclopentamethylenedithiocarbamate (piperidine-1-carbodithioate) [Hg2{S2CN(CH2)5}4] was synthesized and its chemisorption activity toward a solution of AuCl3 in 2 M HCl was studied. The chemisorption of gold from the solution forms an ionic gold(III)‒mercury(II) dithiocarbamato-chlorido complex comprising three isomeric gold cations and an unsymmetrical hexachlorodimercurate anion. The structural organization and thermal behavior of the resulting compounds was studied.

Author information
  • Institute of Geology and Nature Management, Far-East Branch, Russian Academy of Sciences, per. Relochnyi 1, Blagoveshchensk, 675000, RussiaO. V. Loseva & A. V. Ivanov
  • Amur State University, Blagoveshchensk, RussiaT. A. Rodina
  • Luleå University of Technology, Luleå, SwedenO. N. Antzutkin
  • University of Warwick, Coventry, United KingdomO. N. Antzutkin
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